Method of producing vinyl acetate from methyl acetate through hydroformylation
A technology of methyl acetate and vinyl acetate, applied in the field of methyl acetate hydroformylation to produce vinyl acetate, can solve the problems of low vinyl acetate yield and low selectivity, and achieve improved activity and stability, increased yield and selective effect
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Embodiment 1
[0027] Preparation of carbonylation catalyst: CoCl containing 8.30gCo, 2.80gB and 3.30gZn 2 ·6H 2 O, ammonium pentaborate ((NH 4 )B 5 o 8 ·8H 2 O) and zinc gluconate (C 12 h 22 o 14 Zn 3 ·3H 2 O) fully mixed and dissolved in pure water to obtain 400ml of impregnation solution, and the specific surface of 1.0L was 165m 2 / g, spherical SiO with a pore volume of 0.95 and a diameter of 5.6mm 2The carrier was immersed in the above impregnating solution, left to stand for 2 hours and dried at 100° C. to obtain the catalyst. The carbonylation catalyst was analyzed by ICP and ICP-MS, and the Co content was 8.30 g / L, the B content was 2.80 g / L, and the Zn content was 3.30 g / L.
[0028] Synthesis of vinyl acetate:
[0029] Step (1): Add 1.5 mol of acetic acid, 0.05 mol of carbonylation catalyst, 0.10 mol of methyl iodide and 0.45 mol of methyl acetate into a 500ml titanium reactor, first use argon to discharge the air in the reactor and pressurize to 2.0MPa, then Inject car...
Embodiment 2
[0034] Preparation of carbonylation catalyst: CoCl containing 8.30gCo, 2.80gB and 3.30gRb 2 ·6H 2 O, ammonium pentaborate ((NH 4 )B 5 o 8 ·8H 2 O) and RbOAc are fully mixed and dissolved in pure water to obtain 400ml of impregnation solution, and the specific surface of 1.0L is 165m 2 / g, spherical SiO with a pore volume of 0.95 and a diameter of 5.6mm 2 The carrier was immersed in the above impregnating solution, left to stand for 2 hours and dried at 100° C. to obtain the catalyst. The carbonylation catalyst was analyzed by ICP and ICP-MS, and the Co content was 8.30 g / L, the B content was 2.80 g / L, and the Rb content was 3.30 g / L.
[0035] Synthesis of vinyl acetate:
[0036] Step (1): Add 1.5 mol of acetic acid, 0.05 mol of carbonylation catalyst, 0.10 mol of methyl iodide and 0.45 mol of methyl acetate into a 500ml titanium reactor, first use argon to discharge the air in the reactor and pressurize to 2.0MPa, then Introduce carbon monoxide and hydrogen until the p...
Embodiment 3
[0050] Preparation of carbonylation catalyst: NiCl containing 7.00gNi, 1.00gB and 1.00gZn 2 ·6H 2 O, boric acid (H 3 BO 3 ) and zinc citrate (Zn 3 (C 6 h 5 o 7 ) 2 2H 2 O) fully mixed and dissolved in pure water to obtain 400ml of impregnation solution, and the specific surface of 1.0L was 150m 2 / g, spherical Al with a pore volume of 0.90 and a diameter of 5.6mm 2 o 3 The carrier was immersed in the above impregnating solution, left to stand for 2 hours and dried at 80° C. to obtain the catalyst. The carbonylation catalyst was analyzed by ICP and ICP-MS, and the Ni content was 7.00 g / L, the B content was 1.00 g / L, and the Zn content was 1.00 g / L.
[0051] Synthesis of vinyl acetate:
[0052] Step (1): Add 1.5 mol of acetic acid, 0.05 mol of carbonylation catalyst, 0.10 mol of methyl iodide and 0.45 mol of methyl acetate into a 500ml titanium reactor, first use argon to discharge the air in the reactor and pressurize to 2.0MPa, then Introduce carbon monoxide and h...
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