Cold-resistant and light-resistant NBR sole material and preparation method thereof

A shoe sole material and light-resistant technology, applied in the field of shoe sole materials, can solve problems such as cold resistance, poor light aging resistance, service life impact, and performance decline, and achieve the effects of improving light aging resistance, improving cold resistance, and reducing photodegradation

Inactive Publication Date: 2017-09-29
清远市协荣塑胶制品有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this material still has certain defects: poor cold resistance and light aging resistance, easy to embrittle when used in cold environments, and vulnerable to photochemical degradation by ultraviolet rays when used outdoors, with serious performance decline and limited service life. affected

Method used

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  • Cold-resistant and light-resistant NBR sole material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] A cold-resistant and light-resistant NBR shoe sole material, made of the following components by weight: 100 parts of NBR, 5 parts of DOP, 14 parts of calcium carbonate, 3.6 parts of calcium-zinc composite stabilizer, 3.4 parts of carbon black, 2.5 parts of anti-aging agent RD 1.8 parts of sulfur, 1.6 parts of accelerator DZ, 5 parts of compatibilizer SEBS, 7.5 parts of modified nano tin oxide, 10 parts of PPO / PS, 1.5 parts of stearic acid, 4.8 parts of zinc oxide powder.

[0027] The steps of its preparation method are as follows:

[0028] (1) Add nano-tin oxide powder into deionized water, and ultrasonically disperse for 12 minutes to obtain a slurry with a mass fraction of 15%. After adding PEG20000, continue ultrasonically dispersing for 15 minutes, move to a reflux container at 80°C for 3 hours, and cool After reaching room temperature, the material is discharged, dried to constant weight after filtration, and modified nano-tin oxide is obtained after grinding;

...

Embodiment 2

[0032] A cold-resistant and light-resistant NBR shoe sole material, made of the following components in parts by weight: 100 parts of NBR, 7 parts of DOP, 12 parts of calcium carbonate, 3.2 parts of calcium-zinc composite stabilizer, 4 parts of carbon black, 2.4 parts of anti-aging agent RD 1.2 parts of sulfur, 1.5 parts of accelerator DZ, 6 parts of compatibilizer SEBS, 8.5 parts of modified nano tin oxide, 9 parts of PPO / PS, 1.2 parts of stearic acid, 5 parts of zinc oxide powder.

[0033] The steps of its preparation method are as follows:

[0034] (1) Add nano-tin oxide powder into deionized water, and ultrasonically disperse for 12 minutes to obtain a slurry with a mass fraction of 15%. After adding PEG20000, continue ultrasonically dispersing for 15 minutes, move to a reflux container at 80°C for 3 hours, and cool After reaching room temperature, the material is discharged, dried to constant weight after filtration, and modified nano-tin oxide is obtained after grinding;...

Embodiment 3

[0038] A cold-resistant and light-resistant NBR shoe sole material, made of the following components in parts by weight: 100 parts of NBR, 6.5 parts of DOP, 11 parts of kaolin, 4 parts of calcium-zinc composite stabilizer, 3 parts of carbon black, and 1.5 parts of anti-aging agent RD , 1.4 parts of sulfur, 1.4 parts of accelerator DZ, 5.5 parts of compatibilizer SEBS, 8 parts of modified nano-tin oxide, 11 parts of PPO / PS, 1 part of stearic acid, 4.2 parts of zinc oxide powder.

[0039] The steps of its preparation method are as follows:

[0040] (1) Add nano-tin oxide powder into deionized water, and ultrasonically disperse for 12 minutes to obtain a slurry with a mass fraction of 15%. After adding PEG20000, continue ultrasonically dispersing for 15 minutes, move to a reflux container at 80°C for 3 hours, and cool After reaching room temperature, the material is discharged, dried to constant weight after filtration, and modified nano-tin oxide is obtained after grinding;

[00...

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Abstract

The invention provides a cold-resistant and light-resistant NBR (nitrile-butadiene rubber) sole material, which is prepared from the following ingredients in parts by weight: 100 parts of NBR, 5 to 7 parts of plasticizing agents, 10 to 14 parts of filling materials, 3 to 4 parts of thermal stabilizers, 3 to 4 parts of strengthening agents, 2 to 3 parts of age inhibitors, 1 to 2 parts of vulcanizing agents, 1 to 2 parts of accelerating agents, 5 to 6 parts of compatilizers, 7 to 9 parts of nanometer tin dioxide, 9 to 12 parts of PPO / PS, 1 to 2 parts of stearic acid and 4 to 5 parts of zinc oxide. The invention also provides a preparation method of the sole material. The sole material provided by the invention has the advantages of good cold resistance, good light aging-resistant performance and long service life.

Description

Technical field: [0001] The invention relates to a shoe sole material, in particular to a cold-resistant and light-resistant NBR shoe sole material and a preparation method thereof. Background technique: [0002] Nitrile Butadiene Rubber, English name Nitrile Butadiene Rubber, referred to as NBR, is made from butadiene and acrylonitrile by emulsion polymerization. Butadiene monomer can be copolymerized into three different chain structures: cis, trans and 1,2-alkyl. The trans form accounts for about 78% in a typical NBR structure. Because of the cyano group in the molecular chain structure of NBR, its oil resistance (such as resistance to mineral oil, liquid fuel, animal and vegetable oils and solvents) is better than natural rubber, neoprene and styrene-butadiene rubber. Compared with other rubbers, NBR has a wider The operating temperature of the domain. NBR has good chemical stability and good processing performance. With the increase of the content of acrylonitrile in...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L9/02C08L71/12C08L25/06C08L53/02C08K13/06C08K9/10C08K3/26C08K3/22A43B13/04
CPCA43B13/04C08K2201/011C08L9/02C08L2201/08C08L2205/035C08L2205/08C08L71/12C08L25/06C08L53/025C08K13/06C08K9/10C08K2003/2231C08K2003/265C08K2003/2296
Inventor 林立荣
Owner 清远市协荣塑胶制品有限公司
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