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Modified graphene coated lithium manganate battery cathode material and preparation method thereof

A graphene-coated, positive-electrode material technology, applied in the direction of battery electrodes, circuits, electrical components, etc., can solve problems such as restricting development prospects, lack of manganese resources, and high prices, and achieve extended storage time, improved self-discharge, and low cost Effect

Inactive Publication Date: 2016-04-20
王晓伟
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Since the commercialization of lithium-ion batteries, most of the positive electrode materials used in lithium-ion batteries are lithium manganate, lithium manganate or ternary materials, etc., and its components are mainly active materials plus conductive agents and binders. The active materials It is lithium manganate, lithium manganate or ternary, etc.; most of the negative electrode materials use graphite as the active material, and then add some conductive agent and binder; its advantages are high capacity and long cycle life, but manganese resources are scarce and expensive And it is toxic, so it is an important research direction for lithium-ion batteries to seek cheap, reliable, and environmentally friendly cathode materials.
Spinel-type positive electrode materials represented by lithium manganate and layered oxides of ternary materials have been widely studied in the past decade, but their development prospects are restricted by their respective defects.

Method used

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Embodiment Construction

[0011] The modified graphene-coated lithium manganate cathode material is prepared in parts by weight from the following components according to the ratio shown: graphene oxide 60, lithium manganate 30, 45% lithium iron nitrate solution 18, scale Graphite 1, bonding material 1. .

[0012] The preparation method of the modified graphene-coated lithium manganate cathode material comprises the following steps:

[0013] (1) Get graphite and sodium nitrate, place a certain amount of ice-bathed concentrated sulfuric acid in a mass ratio of 2:1, add potassium permanganate 3 times the quality of graphite under stirring, mix well, and control the temperature to be low Stir at 20°C for about 1h, then increase the temperature to 32-38°C for 2h, slowly add quantitative deionized water dropwise, stir well, add hydrogen peroxide to terminate the reaction when the system temperature drops, filter, wash, dry; heat and stir In the process of adding a certain amount of uniformly dispersed car...

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Abstract

The invention relates to a modified graphene coated lithium manganate battery cathode material and a preparation method thereof. The modified graphene coated lithium manganate battery cathode material is prepared from the following components in parts by weight: 60 parts of graphene oxide, 30 parts of lithium manganate, 18 parts of 45% lithium iron nitrate solution, 1 part of flake graphite and 1 part of binding material. The modified graphene coated lithium manganate battery cathode material has the effect of overcoming the defect of lithium ion battery failure caused by self-discharge of protection boards, thus improving self-discharge of a whole battery pack, achieving the aim of prolonging the lithium battery storage time and ensuring that lithium batteries can be stored for a longer time under the condition that users do not charge the lithium batteries after using electric appliances.

Description

technical field [0001] The invention relates to a modified graphene-coated lithium manganate cathode material and a preparation method thereof. Background technique [0002] Since the commercialization of lithium-ion batteries, most of the positive electrode materials used in lithium-ion batteries are lithium manganate, lithium manganate or ternary materials, etc., and its components are mainly active materials plus conductive agents and binders. The active materials It is lithium manganate, lithium manganate or ternary, etc.; most of the negative electrode materials use graphite as the active material, and then add some conductive agent and binder; its advantages are high capacity and long cycle life, but manganese resources are scarce and expensive And it is toxic, so it has become an important research direction for lithium-ion batteries to seek cheap, reliable, and environmentally friendly cathode materials. Spinel-type cathode materials represented by lithium manganate...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/36H01M4/505H01M4/62H01M10/0525
CPCH01M4/366H01M4/505H01M4/625H01M10/0525Y02E60/10
Inventor 王晓伟
Owner 王晓伟
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