Method for separating and purifying lime kiln tail gas
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A lime kiln and tail gas technology, applied in the chemical industry, can solve problems such as pollution, reduce investment and be beneficial to popularization and application.
Inactive Publication Date: 2016-03-23
CHINA TIANCHEN ENG +2
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[0002] The main raw materials of the electric arc calcium carbide production process include coke and lime, among which lime is obtained by calcining limestone in a lime kiln. A large amount of lime kiln tail gas will be produced during the lime kiln calcining process, and the lime kiln tail gas contains 28-35% of CO 2 Gas, traditional process waste gas is directly discharged into the atmosphere after dust removal reaches the standard, causing serious pollution
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Embodiment 1
[0046] The method for separating and purifying lime kiln tail gas comprises the following steps:
[0047] (1) A single gas-fired lime kiln with a daily output of 600 tons of lime, with a tail gas emission of 55,000 Nm 3 / h, the tail gas temperature is 150°C, and the pressure is 4000PaG; it will contain 35% CO 2 , 55%N 2 , 8%H 2 O, 2% O 2 , Dust 30mg / Nm 3 and trace amounts of CO and SO 2 The high-temperature tail gas is passed into the water washing tower for spraying, and the sprayed tail gas is passed into the desulfurization tower for desulfurization treatment;
[0048] (2) The tail gas after desulfurization is passed into the MEA absorption tower, and the monoethanolamine solution in the MEA absorption tower absorbs the carbon dioxide in the tail gas, and the monoethanolamine solution after absorbing carbon dioxide is sent to the analysis tower, and the carbon dioxide is released after expansion and decompression ;
[0049] (3) The released carbon dioxide is pressuri...
Embodiment 2
[0052] The method for separating and purifying lime kiln tail gas comprises the following steps:
[0053] (1) A single gas-fired lime kiln with a daily output of 150 tons of lime, with a tail gas emission of 40,000Nm 3 / h, the tail gas temperature is 130°C, and the pressure is 4000PaG; it will contain 28% CO 2 , 60%N 2 , 8%H 2 O, 4% O 2 , Dust 30mg / Nm 3 and trace amounts of CO and SO 2 The high-temperature tail gas is passed into the water washing tower for spraying, and the sprayed tail gas is passed into the desulfurization tower for desulfurization treatment;
[0054] (2) The tail gas after desulfurization is passed into the MEA absorption tower, and the monoethanolamine solution in the MEA absorption tower absorbs the carbon dioxide in the tail gas, and the monoethanolamine solution after absorbing carbon dioxide is sent to the analysis tower, and the carbon dioxide is released after expansion and decompression ;
[0055] (3) The released carbon dioxide is pressuriz...
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Abstract
The invention provides a method for separating and purifying lime kiln tail gas. The method comprises the following steps: (1) introducing the tail gas discharged from a lime kiln into a washing tower to be sprinkled, introducing the sprinkled tail gas into a desulphurization tower, and performing the desulphurization treatment; (2) introducing the desulphurized tail gas into an MEA absorption tower, allowing a monoethanolamine solution in the MEA absorption tower to absorb carbon dioxide in the tail gas, sending the monoethanolamine solution absorbing the carbon dioxide into a parsing tower, performing the volume expansion and decompression, and then releasing the carbon dioxide; (3) pressurizing, dehydrating and filtering the released carbon dioxide, and then introducing the carbon dioxide into a purification absorption tower to remove impurities; and (4) discharging the tail gas from the MEA absorption tower, pressurizing, dehydrating and filtering the tail gas, then introducing the tail gas into the purification absorption tower to remove impurities, and obtaining nitrogen. By adopting the method for separating and purifying the lime kiln tail gas, the waste gas can be converted into treasure. Not only is the requirement on the national industrial structural adjustment and environmental protection policies met, but also certain economic benefit can be brought to the enterprises.
Description
technical field [0001] The invention belongs to the field of chemical industry, and in particular relates to a method for separating and purifying lime kiln tail gas. Background technique [0002] The main raw materials of the electric arc calcium carbide production process include coke and lime, among which lime is obtained by calcining limestone in a lime kiln. A large amount of lime kiln tail gas will be produced during the lime kiln calcining process, and the lime kiln tail gas contains 28-35% of CO 2 Gas, traditional process waste gas is directly discharged into the atmosphere after dust removal reaches the standard, causing serious pollution. In order to achieve the goal of low-carbon emissions in industrialization, the country clearly put forward carbon emission control indicators in the "Government Work Report" and "Thirteenth Five-Year Plan", and established carbon emission exchanges one after another to encourage enterprises to adopt energy-saving and emission-red...
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