High-purity sulfur/charcoal-coated lithium cobalt oxide positive electrode material and preparation method thereof

Abstract

The invention relates to a high-purity sulfur / charcoal-coated lithium cobalt oxide positive electrode material and a preparation method thereof. The high-purity sulfur / charcoal-coated lithium cobalt oxide positive electrode material is prepared from the following components by weight: 30 parts of a sulfur / charcoal composite material, 60 parts of lithium cobalt oxide, 25 parts of a lithium ferric nitrate solution with a concentration of 45%, 3 parts of flake graphite and 3 parts of a bonding material. The high-purity sulfur / charcoal-coated lithium cobalt oxide positive electrode material overcomes the defect of failure caused by self-discharging of a protection plate of a lithium ion battery, so self-discharging of a whole battery pack is improved, the purpose of prolongation of the storage time of the lithium battery is achieved, and it is guaranteed that the lithium battery can be stored for a long time under the condition that a user does not charge an electric appliance after usage.

Description

technical field [0001] The invention relates to a high-purity sulfur / carbon-coated lithium cobalt oxide cathode material and a preparation method thereof. Background technique [0002] Since the commercialization of lithium-ion batteries, most of the positive electrode materials used in lithium-ion batteries are lithium cobaltate, lithium manganate or ternary materials, etc., and its components are mainly lithium cobaltate plus conductive agent and then binder. Lithium oxide is lithium cobaltate, lithium manganese oxide or ternary, etc.; most of the negative electrode materials use graphite as the active material, and then add some conductive agent and binder; its advantages are high capacity and long cycle life, but cobalt resources are scarce, It is expensive and toxic, so it is an important research direction for lithium-ion batteries to seek cheap, reliable, and environmentally friendly cathode materials. Spinel-type cathode materials represented by lithium manganate an...

AI Technical Summary

Problems solved by technology

[0002] Since the commercialization of lithium-ion batteries, most of the positive electrode materials used in lithium-ion batteries are lithium cobaltate, lithium manganate or ternary materials, etc., and its components are mainly lithium cobaltate plus conductive agent and then binder. Lithium oxide is lithium cobaltate, lithium manganese oxide or ternary, etc.; most of the negative electrode materials use graphite as the active material, and then add some conductive agent and binder; its advantages are high capacity and long cycle life, but cobalt resources are scarce, Expensive and toxic, so it is an important research direction for lithium-ion batteries to seek affordable, reliable, and environmentally friendly cathode materials

Spinel-type positive electrode materials represented by lithium manganate and layered oxides of ternary materials have been widely studied in the past decade, but their development prospects are restricted by their respective defects.