Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Low-voc polyurethane matte varnish and preparation method thereof

A polyurethane and matte technology, applied in polyurea/polyurethane coatings, coatings, etc., can solve the problems of dry paint film, low solid content in construction, poor fullness, etc., and achieve high solid content in construction and plump paint film , the effect of reducing the number of coating layers

Active Publication Date: 2017-11-17
SKSHU PAINT
View PDF3 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the VOC content of PU wood paint coatings on the market is higher than 420 g / L, and the VOC is collected in the production, commissioned processing and import links, which not only increases the cost, but also pollutes the environment, and is difficult to be welcomed by consumers.
On the other hand, for PU matte varnishes, the solid content is often low in construction, and the VOC content during spraying construction is basically above 600 g / L, which is much higher than the index of 420 g / L. At the same time, the paint film is easy to dry out and lack fullness Therefore, preparing a low-VOC polyurethane matt varnish is a problem that technical personnel need to overcome together

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Low-voc polyurethane matte varnish and preparation method thereof
  • Low-voc polyurethane matte varnish and preparation method thereof
  • Low-voc polyurethane matte varnish and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

specific Embodiment approach

[0031] A low-VOC polyurethane glossy varnish, characterized in that: it is prepared from component A and component B in a weight ratio of 1:0.8-1.2;

[0032] The first component is made from the raw materials of the following weight ratio:

[0033]

[0034]

[0035] The B component is made from the raw materials of the following weight ratio:

[0036] TDI trimer 50-70 parts,

[0037] HDI trimer 20-40 parts,

[0038] 15-30 parts of butyl acetate.

[0039] Further, the high-solid and low-viscosity alkyd resin is prepared from the following components in the following parts by weight ratio:

[0040]

[0041] The reflux solvent is one of xylene and toluene. The diluted solvent is one of xylene, butyl acetate and ethyl acetate.

[0042] The fatty acid is one of soybean oil fatty acid, castor oil fatty acid and octadecenoic acid. The No. 1 polyol is one or both of pentaerythritol or trimethylolpropane mixed in any proportion; the No. 2 polyol is one or both of neopent...

Embodiment 1

[0060] Add 24.77g of soybean oil fatty acid, 15.13g of pentaerythritol, 0.11g of hypophosphorous acid, and 4.13g of xylene into a four-neck flask with a stirring device in sequence, stir evenly, heat up, and heat up to 205-220 degrees in 1-2 hours, and keep warm for the reaction 1-2 hours, then cool down to below 190 degrees, add 5.26g neopentyl glycol, 5.77g diethylene glycol, 0.61g maleic anhydride, 27.79g phthalic anhydride, continue to heat up, at 200- React at 220°C until the acid value is less than 14mgKOH / g, viscosity 4-7S / div, 25°C, then cool down to below 150°C, add 16.43g of butyl acetate, stir evenly for 0.5 hours, and discharge.

Embodiment 2

[0062] Add 28.66g of soybean oil fatty acid, 14.99g of pentaerythritol, 0.14g of hypophosphorous acid, and 4g of xylene into a four-necked flask with a stirring device in sequence, stir evenly, heat up, and heat up to 205-220 degrees in 1-2 hours. -2 hours, then cool down to below 190 degrees, add 4.82g neopentyl glycol, 5.50g diethylene glycol, 26.89g phthalic anhydride, continue to heat up, react at 200-220 degrees, until the acid value is less than 14mgKOH / g, viscosity 4-7S / grid, 25 degrees, then lower the temperature to below 150 degrees, add 15g xylene, stir evenly for 0.5 hours, and discharge.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
particle diameteraaaaaaaaaa
particle diameteraaaaaaaaaa
particle diameteraaaaaaaaaa
Login to View More

Abstract

The invention relates to a low-VOC polyurethane matt varnish and a preparation method thereof. It is prepared from components A and B at a ratio of 1:0.8-1.2. A is composed of the following components: high-solid and low-viscosity alkyd resin, dispersant , defoamer No. 1, anti-settling slurry, matting powder, leveling agent, defoamer No. 2, drier, composite environmental protection solvent; B is composed of the following components: TDI trimer, HDI trimer, acetic acid butyl ester. The beneficial effects of the present invention are as follows: it can reduce the VOC content during coating construction and achieve the purpose of exempting consumption tax; it can reduce the number of coating layers of paint, so it helps to reduce costs and save raw materials; the paint film is smooth and transparent, and improves the quality of woodenware The grade of paint.

Description

technical field [0001] The invention relates to a low-VOC polyurethane matte varnish and a preparation method thereof. Background technique [0002] In order to promote energy conservation and environmental protection, from February 1, 2015, consumption tax will be levied on paints with a volatile organic compound (VOC) content higher than 420 mg / L (inclusive) under construction. At present, the VOC content of PU wood paint coatings on the market is higher than 420 g / L, and the collection in the production, commissioned processing and import links will not only increase the cost, but also pollute the environment, making it difficult to be welcomed by consumers. On the other hand, for PU matte varnishes, the solid content is often low in construction, and the VOC content during spraying construction is basically above 600 g / L, which is much higher than the index of 420 g / L. At the same time, the paint film is easy to dry out and lack fullness Therefore, preparing a kind of l...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C09D175/14C09D7/12C08G63/49
Inventor 洪杰张胜军赵子千王新潮
Owner SKSHU PAINT
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products