Preparation method of cage-shaped organic silicon hybridized star-shaped polyester soft PVC plasticizer
An organosilicon and plasticizer technology, applied in the field of functional polymer material preparation and modification, can solve problems such as increasing low temperature impact resistance, achieve enhanced low temperature impact resistance, good compatibility, and prevent plasticizer migration Effect
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Embodiment 1
[0032] A kind of preparation method of cage silicone hybrid star polyester soft PVC plasticizer, its preparation steps are as follows:
[0033] S1, ricinoleic acid is subjected to cracking and oxidation through ozone oxidation, and Renay-Ni catalytic hydrogenation reaction to obtain nonanol acid and 1,3-dihydroxynonanediol;
[0034] S2. The vertex group of octamethacryloyloxypropyl cage silsesquioxane undergoes an ester hydrolysis reaction in aqueous sulfuric acid, and stirs and refluxes for 4 hours to obtain octapropanol cage silsesquioxane;
[0035] S3, the nonanol acid obtained in step S1 and 1,3-dihydroxynonanediol and the octapropanol-based cage silsesquioxane obtained in step S2 are 70:10:20 in mass ratio with dimer acid Mix to obtain a mixed solution;
[0036] S4, adding esterification reaction catalyst heteropolyacid PW to the mixed solution prepared in step S3 12 / SiO 2 And dehydrating agent DCC, reflux reaction for 2~6h, to obtain cage silicone hybrid star polyest...
Embodiment 2
[0039] A kind of preparation method of cage silicone hybrid star polyester soft PVC plasticizer, its preparation steps are as follows:
[0040] S1, ricinoleic acid is subjected to cracking and oxidation through ozone oxidation, and Pd / C catalytic hydrogenation reaction to obtain nonanol acid and 1,3-dihydroxynonanediol;
[0041] S2. The vertex group of octamethacryloxypropyl cage silsesquioxane undergoes an ester hydrolysis reaction in aqueous sodium hydroxide solution, and stirs and refluxes for 2 hours to obtain octapropanol cage silsesquioxane ;
[0042] S3, the nonanol acid obtained in step S1 and 1,3-dihydroxynonanediol and the octapropanol-based cage silsesquioxane obtained in step S2 are 70:20:10 in mass ratio with dimer acid Mix to obtain a mixed solution;
[0043] S4, adding esterification reaction catalyst heteropolyacid PW to the mixed solution prepared in step S3 12 / SiO 2 And dehydrating agent DCC, reflux reaction for 2~6h, to obtain cage silicone hybrid star ...
Embodiment 3
[0045] A kind of preparation method of cage silicone hybrid star polyester soft PVC plasticizer, its preparation steps are as follows:
[0046] S1, ricinoleic acid is subjected to cracking and oxidation through ozone oxidation, and Pd / C catalytic hydrogenation reaction to obtain nonanol acid and 1,3-dihydroxynonanediol;
[0047] S2. The vertex group of octamethacryloyloxypropyl cage silsesquioxane undergoes an ester hydrolysis reaction in aqueous sulfuric acid, and stirs and refluxes for 4 hours to obtain octapropanol cage silsesquioxane;
[0048] S3, the nonanol acid obtained in step S1 and 1,3-dihydroxynonanediol and the octapropanol-based cage silsesquioxane obtained in step S2 are 80:10:10 in mass ratio with dimer acid Mix to obtain a mixed solution;
[0049] S4, adding esterification reaction catalyst heteropolyacid PW to the mixed solution prepared in step S3 12 / SiO 2 And dehydrating agent DCC, reflux reaction for 2~6h, to obtain cage silicone hybrid star polyester sof...
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