Degradable paper plastic composite bag and preparation method thereof
A paper-plastic composite bag and plastic layer technology, applied in the field of composite bag manufacturing, can solve the problems of environmental damage, harsh degradation conditions, poor photodegradability and biodegradability of polypropylene, etc.
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[0025] The present invention also provides a method for preparing a degradable paper-plastic composite bag, the method comprising:
[0026] (1) Starch, plant fiber, polyvinyl alcohol, poly-β-hydroxybutyrate, polyethylene, polycarbonate, nano-titanium dioxide, glycerin, plasticizer and stabilizer are mixed and extruded to form a film;
[0027] (2) The film is heated and coated on the surface of the paper layer to form a plastic layer to make a composite paper; or the film is cut, drawn, and woven into a plastic layer, and then the plastic layer is glued Adhesive is stuck on the surface of described paper layer to make composite paper;
[0028] (3) Processing the composite paper machine into a degradable paper-plastic composite bag.
[0029] In the above preparation method, the specific type of starch can be selected in a wide range, which can be wheat starch and potato starch, and can also be sweet potato starch and mung bean starch. At the same time, the molecular weight of ...
Embodiment 1
[0044] (1) At 25°C, wheat starch (weight-average molecular weight is 16000), rice husk (weight-average molecular weight is 17000), polyvinyl alcohol (weight-average molecular weight is 18000), poly-β-hydroxybutyrate (weight-average Molecular weight is 19000), polyethylene (weight-average molecular weight is 18000), polycarbonate (weight-average molecular weight is 20000), nano-titanium dioxide (particle diameter 400nm), glycerin, plasticizer and stabilizer (the mass ratio of each raw material is successively 100:12:20:12:12:16:4:2:4:3) mixed for 2 hours, and extruded at 240°C to obtain a film.
[0045] (2) cutting, drawing and weaving the film into a plastic layer, and then the plastic layer is adhered to the surface of the paper layer by an adhesive to make a composite paper (a combination of the paper layer and the plastic layer) The thickness ratio is 1.1:1).
[0046] (3) Process the above-mentioned composite paper machine into a degradable paper-plastic composite bag A1. ...
Embodiment 2
[0049] (1) At 25°C, potato starch (weight-average molecular weight is 12000), straw plant fiber (weight-average molecular weight is 15000), polyvinyl alcohol (weight-average molecular weight is 16000), poly-β-hydroxybutyrate (weight-average Average molecular weight is 12000), polyethylene (weight average molecular weight is 14000), polycarbonate (weight average molecular weight is 18000), nano-titanium dioxide (particle diameter 300nm), glycerin, plasticizer and stabilizer (the mass ratio of each raw material is sequential (100:10:15:5:10:12:5:1:3:2) were mixed for 2 hours, and extruded at 240°C to obtain a film.
[0050] (2) The film is cut, drawn, and woven into a plastic layer, and then the plastic layer is adhered to the surface of the paper layer by an adhesive to make a composite paper (the combination of the paper layer and the plastic layer) The thickness ratio is 1.2:1).
[0051] (3) Process the above-mentioned composite paper machine into a degradable paper-plastic ...
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