Yellow green phosphorescent cuprous complex luminous material based on diphenyleneimine
A technology of luminescent materials and complexes, which is applied in the direction of luminescent materials, copper organic compounds, compounds of group 5/15 elements of the periodic table, etc. Limitation and other issues, achieve good phosphorescence emission performance, promote inter-system crossing, and simple equipment
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Embodiment 1
[0030] A large number of phosphorescent complexes CuI(o-Tol 3 P) Preparation of (DAF) microcrystalline samples: Weigh 0.5 mmol of CuI and dissolve it in 25 mL of acetonitrile, weigh 0.5 mmol of tris(2-tolyl)phosphine ligand and dissolve it in 15 mL of acetone, and mix the two solutions , and stirred to make it fully undergo a coordination reaction to obtain a colorless solution A; then weigh 0.5 mmol of DAF ligand and dissolve it in 15 mL of acetone, then add this solution to the above solution A, and stir to make it fully undergo a coordination reaction , and finally the resulting yellow reaction solution was rotary evaporated to remove all solvents, and dried in vacuum to obtain a yellow needle-like fine crystal powder as the product, with a yield of 98% (calculated as Cu). Calculated by elemental analysis (C32H29N2PCuI): C, 57.97%; H, 4.41%; N, 4.23%. Experimental values: C, 58.60%; H, 4.40%; N, 4.11%. IR (KBr pellet, cm -1 ): 3449m, 3045m, 2958m, 1935w, 1588m, 1574m, 15...
Embodiment 2
[0032] Synthesis of Phosphorescent Cuprous Complex CuI(o-Tol 3 P) Single crystal of (DAF): CuI (0.019 g, 0.1 mmol) was dissolved in 8 ml of acetonitrile, ligand 4,5-diazafluorene (0.017 g, 0.1 mmol) and tris(2-tolyl) Phosphine (0.030g, 0.1mmol) was dissolved in 8ml of acetone. After complete dissolution, the two were mixed, stirred for 5min, and then filtered to obtain a yellow clear solution. The filtrate was placed in a 25ml Erlenmeyer flask, covered with a plastic wrap, pierced with a needle and crystallized by volatilization. After about 3 days, yellow needle-like crystals were obtained. A yellow needle-like transparent crystal with a size of 0.35mm×0.23mm×0.12mm was selected for X-ray single crystal diffraction structure test. The molecular structure of the compound is shown in the attached figure 1 , and its unit cell packing structure is shown in the attached figure 2 .
[0033] p-phosphorescent cuprous complex CuI(o-Tol 3 A series of performance tests were carri...
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