Micro-surfacing slow cracking and rapid setting asphalt emulsifier and preparation method thereof
A technology of asphalt emulsifier and solvent, which is applied in the field of slow-cracking and fast-setting asphalt emulsifier for micro-surface and its preparation field, which can solve the complicated preparation process of emulsifier, poor adaptability of asphalt and aggregate, and poor slow-cracking and fast-setting effect Good and other problems, to achieve good emulsifying ability, uniform and fine particles, easy to industrial production
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Embodiment 1
[0027] Add lauric acid and ethylenediamine with a molar ratio of 1:1.4 into a three-necked flask, and add o-xylene accounting for 40wt% of the total weight of the reaction raw materials, stir and heat up to 160°C, and carry out amidation reaction at a constant temperature for 2.0 hours, and then Under vacuum conditions (vacuum degree 0.092MPa), the temperature of the reaction system was raised to 240°C, and the cyclization reaction was continued for 4.0 hours to remove the solvent and generated water to obtain an intermediate. After the temperature dropped to 90°C, it was mixed with the intermediate The methyl acrylate compound with a volume molar ratio of 1:1.3 was prepared as a 90wt% ethanol solution, and was slowly added dropwise to the intermediate. After the dropwise addition, it was stirred at 100°C for an addition reaction for 3.0 hours to obtain asphalt emulsification agent products.
[0028] The asphalt emulsifier prepared above is prepared as an aqueous solution acco...
Embodiment 2
[0033] Add capric acid and ethylenediamine with a molar ratio of 1:1 into a three-necked flask, and add toluene accounting for 20wt% of the total weight of the reaction raw materials, stir and heat up to 140°C, carry out amidation reaction at a constant temperature for 4.0 hours, and then Under the conditions (vacuum degree 0.092MPa), the temperature of the reaction system was raised to 220°C, and the cyclization reaction was continued for 6.0 hours to remove the solvent and the generated water to obtain the intermediate. After the temperature dropped to 70°C, the mole of the intermediate The methyl acrylate compound with a ratio of 1:1.0 was prepared as a 70wt% ethanol solution, and slowly added dropwise to the intermediate. After the dropwise addition was completed, it was stirred at 80°C for an addition reaction for 1.0 hours, and the asphalt emulsifier product was obtained .
[0034] The asphalt emulsifier prepared above is formulated into an aqueous solution according to ...
Embodiment 3
[0039] Add capric acid and ethylenediamine with a molar ratio of 1:1.2 into a three-necked flask, and add m-xylene accounting for 30wt% of the total weight of the reaction raw materials, stir and heat up to 150°C, and carry out amidation reaction at a constant temperature for 3.0 hours, and then Under vacuum conditions (vacuum degree 0.092MPa), raise the temperature of the reaction system to 230°C, continue the cyclization reaction for 5.0 hours, remove the solvent and the generated water to obtain the intermediate, and after the temperature drops to 80°C, combine with the intermediate The ethyl acrylate compound with a volume molar ratio of 1:1.2 was prepared as an 80wt% ethanol solution, and slowly added dropwise to the intermediate. After the dropwise addition was completed, the addition reaction was carried out at 90°C for 2.0 hours to obtain asphalt emulsification agent products.
[0040] The asphalt emulsifier for micro-surfacing prepared above is formulated into an aque...
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