Slow-cracking and fast-setting asphalt emulsifier for micro-surfacing and preparation method thereof
A technology of asphalt emulsifier and solvent, which is applied in the field of slow-cracking and fast-setting asphalt emulsifier for micro-surface and its preparation, which can solve the problems of cumbersome emulsifier preparation process, poor adaptability of asphalt and aggregates, and difficult control of demulsification rate, etc. problems, to achieve good emulsifying ability, uniform and fine particles, and easy industrial production
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Embodiment 1
[0027] Add lauric acid and ethylenediamine with a molar ratio of 1:1.4 into a three-necked flask, and add o-xylene accounting for 40wt% of the total weight of the reaction raw materials, stir and heat up to 160°C, and carry out amidation reaction at a constant temperature for 2.0 hours, and then Under vacuum conditions (vacuum degree 0.092MPa), the temperature of the reaction system was raised to 240°C, and the cyclization reaction was continued for 4.0 hours to remove the solvent and generated water to obtain an intermediate. After the temperature dropped to 90°C, it was mixed with the intermediate The methyl acrylate compound with a volume molar ratio of 1:1.3 was prepared as a 90wt% ethanol solution, and was slowly added dropwise to the intermediate. After the dropwise addition, it was stirred at 100°C for an addition reaction for 3.0 hours to obtain asphalt emulsification agent products.
[0028] The asphalt emulsifier prepared above is prepared as an aqueous solution acco...
Embodiment 2
[0033] Add capric acid and ethylenediamine with a molar ratio of 1:1 into a three-necked flask, and add toluene accounting for 20wt% of the total weight of the reaction raw materials, stir and heat up to 140°C, carry out amidation reaction at a constant temperature for 4.0 hours, and then Under the conditions (vacuum degree 0.092MPa), the temperature of the reaction system was raised to 220°C, and the cyclization reaction was continued for 6.0 hours to remove the solvent and the generated water to obtain the intermediate. After the temperature dropped to 70°C, the mole of the intermediate The methyl acrylate compound with a ratio of 1:1.0 was prepared as a 70wt% ethanol solution, and slowly added dropwise to the intermediate. After the dropwise addition was completed, it was stirred at 80°C for an addition reaction for 1.0 hours, and the asphalt emulsifier product was obtained .
[0034] The asphalt emulsifier prepared above is formulated into an aqueous solution according to ...
Embodiment 3
[0039] Add capric acid and ethylenediamine with a molar ratio of 1:1.2 into a three-necked flask, and add m-xylene accounting for 30wt% of the total weight of the reaction raw materials, stir and heat up to 150°C, and carry out amidation reaction at a constant temperature for 3.0 hours, and then Under vacuum conditions (vacuum degree 0.092MPa), raise the temperature of the reaction system to 230°C, continue the cyclization reaction for 5.0 hours, remove the solvent and the generated water to obtain the intermediate, and after the temperature drops to 80°C, combine with the intermediate The ethyl acrylate compound with a volume molar ratio of 1:1.2 was prepared as an 80wt% ethanol solution, and slowly added dropwise to the intermediate. After the dropwise addition was completed, the addition reaction was carried out at 90°C for 2.0 hours to obtain asphalt emulsification agent products.
[0040] The asphalt emulsifier for micro-surfacing prepared above is formulated into an aque...
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