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Slow-cracking and fast-setting asphalt emulsifier for micro-surfacing and preparation method thereof

A technology of asphalt emulsifier and solvent, which is applied in the field of slow-cracking and fast-setting asphalt emulsifier for micro-surface and its preparation, which can solve the problems of cumbersome emulsifier preparation process, poor adaptability of asphalt and aggregates, and difficult control of demulsification rate, etc. problems, to achieve good emulsifying ability, uniform and fine particles, and easy industrial production

Active Publication Date: 2016-11-30
CHINA NAT OFFSHORE OIL CORP +3
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The emulsifier used for emulsified asphalt for micro-surfacing is required to be cationic emulsifier. Practice has proved that the emulsified asphalt prepared by cationic asphalt emulsifier has strong adsorption force on the surface of stone materials, good peeling resistance, fast forming speed and high early strength, but Due to the strong polarity of its hydrophilic group, the demulsification speed is fast, resulting in a short mixing time, and the micro-surface mixture is a cold-mixed cold-paved mixture, which is in a slurry state during construction. Considering Due to the ease of construction and the requirement of rapid open traffic, it is necessary to control the mixing time of emulsified asphalt and aggregate
[0004] At present, asphalt emulsifiers used for micro-surfaces generally have poor slow-cracking and fast-setting effects, poor adaptability to different asphalt and aggregates, difficulty in controlling the demulsification rate, cumbersome emulsifier preparation process, complicated formula, and the need to add a variety of additives, resulting in Its raw material sources are limited and its environmental friendliness is not good.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Add lauric acid and ethylenediamine with a molar ratio of 1:1.4 into a three-necked flask, and add o-xylene accounting for 40wt% of the total weight of the reaction raw materials, stir and heat up to 160°C, and carry out amidation reaction at a constant temperature for 2.0 hours, and then Under vacuum conditions (vacuum degree 0.092MPa), the temperature of the reaction system was raised to 240°C, and the cyclization reaction was continued for 4.0 hours to remove the solvent and generated water to obtain an intermediate. After the temperature dropped to 90°C, it was mixed with the intermediate The methyl acrylate compound with a volume molar ratio of 1:1.3 was prepared as a 90wt% ethanol solution, and was slowly added dropwise to the intermediate. After the dropwise addition, it was stirred at 100°C for an addition reaction for 3.0 hours to obtain asphalt emulsification agent products.

[0028] The asphalt emulsifier prepared above is prepared as an aqueous solution acco...

Embodiment 2

[0033] Add capric acid and ethylenediamine with a molar ratio of 1:1 into a three-necked flask, and add toluene accounting for 20wt% of the total weight of the reaction raw materials, stir and heat up to 140°C, carry out amidation reaction at a constant temperature for 4.0 hours, and then Under the conditions (vacuum degree 0.092MPa), the temperature of the reaction system was raised to 220°C, and the cyclization reaction was continued for 6.0 hours to remove the solvent and the generated water to obtain the intermediate. After the temperature dropped to 70°C, the mole of the intermediate The methyl acrylate compound with a ratio of 1:1.0 was prepared as a 70wt% ethanol solution, and slowly added dropwise to the intermediate. After the dropwise addition was completed, it was stirred at 80°C for an addition reaction for 1.0 hours, and the asphalt emulsifier product was obtained .

[0034] The asphalt emulsifier prepared above is formulated into an aqueous solution according to ...

Embodiment 3

[0039] Add capric acid and ethylenediamine with a molar ratio of 1:1.2 into a three-necked flask, and add m-xylene accounting for 30wt% of the total weight of the reaction raw materials, stir and heat up to 150°C, and carry out amidation reaction at a constant temperature for 3.0 hours, and then Under vacuum conditions (vacuum degree 0.092MPa), raise the temperature of the reaction system to 230°C, continue the cyclization reaction for 5.0 hours, remove the solvent and the generated water to obtain the intermediate, and after the temperature drops to 80°C, combine with the intermediate The ethyl acrylate compound with a volume molar ratio of 1:1.2 was prepared as an 80wt% ethanol solution, and slowly added dropwise to the intermediate. After the dropwise addition was completed, the addition reaction was carried out at 90°C for 2.0 hours to obtain asphalt emulsification agent products.

[0040] The asphalt emulsifier for micro-surfacing prepared above is formulated into an aque...

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Abstract

The invention discloses a slow-cracking and fast-setting asphalt emulsifier for micro-surface and a preparation method thereof. The method for preparing an asphalt emulsifier comprises the following steps: 1) after the organic acid, the organic polyamine and the solvent are mixed and subjected to an amidation reaction, the cyclization reaction is carried out under vacuum conditions, and the solvent and water in the system are removed after the reaction is completed. 2) After the reaction system obtained in step 1) is cooled down, the ethanol solution of the graft modifier is subjected to an addition reaction with the intermediate obtained in step 1), and the asphalt emulsifier is obtained after the reaction is completed. The asphalt emulsifier has a wide range of preparation raw materials, a simple preparation method, mild reaction conditions, environmental friendliness, and easy industrial production. The asphalt emulsifier has good emulsification ability for different asphalts, and the prepared emulsified asphalt has good storage stability, uniform and fine particles, good adaptability to aggregates, and obvious slow cracking and fast setting effect. It can be used to prepare emulsified asphalt for micro-surface.

Description

technical field [0001] The invention belongs to the field of petrochemical industry, and relates to a slow-cracking and fast-setting asphalt emulsifier for micro-surface treatment and a preparation method thereof. Background technique [0002] Micro-surfacing is to use special mechanical equipment to mix polymer-modified emulsified asphalt, coarse and fine aggregates, fillers, water and additives according to the design ratio to form a slurry mixture, spread it on the original road surface, and open the traffic soon. Thin-layer structure with high anti-slip and durable properties. As an important branch of emulsified asphalt technology, micro-surfacing technology is used not only for asphalt pavement, but also for the overlay of cement concrete pavement in foreign countries. In my country, it is mostly used for asphalt pavement, cement concrete bridge deck, tunnel pavement, etc. It is considered to be one of the most effective and economical means to repair road rutting and ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01F17/32C07D207/04C08J3/03C08L95/00C08L9/06C04B26/26C09K23/32
Inventor 甘为民李福起车金良范维玉孔祥军王志超姚秀杰杨乾乾
Owner CHINA NAT OFFSHORE OIL CORP
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