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Nickel-chromium plated parts and method of manufacture

A manufacturing method and component technology, applied in the field of nickel-chromium plated components and their manufacturing, can solve the problems of poor corrosion resistance, inability to meet the requirements of corrosive environments, and unsuitable products.

Active Publication Date: 2017-07-11
JIAXING MINHUI AUTOMOTIVE PARTS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the use of microporous nickel or microcracked nickel alone, the improvement of corrosion resistance is limited; and the combination of microcracks and trivalent chromium has problems such as poor appearance, resulting in inapplicability for products with high corrosion resistance requirements
At the same time, in some existing technologies, it is disclosed to change the microporous nickel process to achieve noble potential characteristics, so as to meet the corrosion resistance requirements of trivalent chromium, but this process technology cannot achieve collinear production with hexavalent chromium and trivalent chromium. All components meet high-quality corrosion-resistant requirements
[0005] In the prior art, for example, the Chinese patent application (publication number: CN 101988211 A) relates to a multi-layer nickel plating process on metal surfaces with excellent anti-corrosion performance. The electroplating process flow is: A. metallization of the surface of plastic parts, B. bright copper , C. semi-bright nickel, D. high-sulfur nickel E. bright nickel, F. microporous nickel, G. washing, H. bright chromium, I. washing, J. drying; although the four-layer nickel is used in this technical scheme The electroplating of nickel electroplating solution on the plastic surface improves the corrosion resistance of plastic parts to a certain extent, but the corrosion resistance of this process is still not as good as that containing deicing salt (CaCl 2 ) Requirements for corrosive environment
And about the technique of introducing micro-crack nickel, as Chinese patent application (publication number: CN101705508A) relates to a kind of electroplating solution and application thereof for micro-crack nickel electroplating, the main composition of this micro-crack nickel electroplating solution is as follows: nickel chloride: 180-260 g / L, acetic acid: 20-60 mL / L, ELPELYT MR: 80-120 mL / L, 62A: 1-5 mL / L, the evaluation of the examples described in the patent literature is actually limited to hexavalent chromium plating , did not talk about trivalent chromium plating, and at the same time, it was verified that there were phenomena such as poor corrosion resistance and inconsistent appearance

Method used

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  • Nickel-chromium plated parts and method of manufacture
  • Nickel-chromium plated parts and method of manufacture
  • Nickel-chromium plated parts and method of manufacture

Examples

Experimental program
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Effect test

Embodiment 1

[0080] The nickel-chromium plating part of the present embodiment, this part comprises: base material 1 (ABS material); Pretreatment plating layer 2 comprises chemical nickel layer 809, makes a bottom nickel layer 808 and copper-plated layer 3, and chemical nickel layer deposits 809 to deposit on On the whole substrate 1, a bottoming nickel layer 808 is deposited on the chemical nickel layer 809, and a copper plating layer 3 is formed on the bottoming nickel layer 808; and a functional layer 4, which is formed on the copper plating layer 3, wherein the functional layer 4 comprising a low-potential nickel layer 141 and a microporous nickel layer 142, wherein the low-potential nickel layer 141 is a high-sulfur nickel layer, the microporous nickel layer 142 formed on the high-sulfur nickel layer; and the microporous nickel layer 142 formed on the microporous nickel layer 142 Decorative layer 802 (trivalent white chrome plating).

Embodiment 2

[0082] The nickel-chromium plating part of the present embodiment, this part comprises: base material 1 (ABS material); Pretreatment plating layer 2 comprises chemical nickel layer 809, makes a bottom nickel layer 808 and copper-plated layer 3, and chemical nickel layer deposits 809 to deposit on On the whole substrate 1, a bottoming nickel layer 808 is deposited on the chemical nickel layer 809, and a copper plating layer 3 is formed on the bottoming nickel layer 808; and a functional layer 4, which is formed on the copper plating layer 3, wherein the functional layer 4 comprising a low-potential nickel layer 141 and a microporous nickel layer 142, wherein the low-potential nickel layer 141 is a microcracked nickel layer, the microporous nickel layer 142 formed on the microcracked nickel layer; and the microporous nickel layer 142 formed on the microporous nickel layer 142 Decorative layer 802 (trivalent black chrome plating).

Embodiment 3

[0084] The nickel-chromium plating part of the present embodiment, this part comprises: base material 1 (ABS material); Pretreatment plating layer 2 comprises chemical nickel layer 809, makes a bottom nickel layer 808 and copper-plated layer 3, and chemical nickel layer deposits 809 to deposit on On the whole substrate 1, a bottoming nickel layer 808 is deposited on the chemical nickel layer 809, and a copper plating layer 3 is formed on the bottoming nickel layer 808; and a functional layer 4, which is formed on the copper plating layer 3, wherein the functional layer 4 includes a low-potential nickel layer 141 and a microporous nickel layer 142, wherein the low-potential nickel layer 141 is a high-sulfur nickel layer and a micro-crack nickel layer (it may be that the high-sulfur nickel layer is formed on the copper plating layer 3, and the micro-crack nickel layer is formed On the high-sulfur nickel layer; it can also be that the micro-crack nickel layer is formed on the copp...

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Abstract

The invention discloses a nickel-chromium plating part and a manufacturing method thereof. The nickel-chromium plating part includes a substrate, a pretreatment coating and a decorative layer. The pretreatment coating is deposited on the entire substrate, and a copper plate layer and a functional layer are formed on the pretreatment coating; the functional layer is formed on the copper plate layer; the functional layer includes a low potential nickel layer and a microporous nickel layer formed on the low potential nickel layer; and the decorative layer is formed on the microporous nickel layer. Based on the micropores on the part surface and chrome plating technology, the low potential nickel layer is added to improve the corrosion resistance of the product, especially the corrosion resistance of trivalent chromium plating product, so as to promote the large scale popularization and application of the trivalent chromium product, which has better environmental protection performance.

Description

technical field [0001] The invention relates to a workpiece with a surface electroplating layer structure and its electroplating technology, in particular to a nickel-chrome plated part and its manufacturing method. [0002] In this application, the potential difference is the difference between the standard potentials measured by taking each of the two adjacent layers as a whole. Background technique [0003] The European market has increasingly stringent environmental protection requirements, and automobile factories have higher and higher requirements for electroplating corrosion resistance. At present, chromium electroplating cannot meet the corrosion requirements of specific environments (at the same time, it can meet the salt spray resistance test of 80h and the Russian mud resistance test. 336h). [0004] In the electroplating industry, the method of firstly plating double-layer nickel or triple-layer nickel and then chromium plating is generally used to improve the ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B32B15/01B32B3/24C25D5/14C25D3/12C25D3/04
Inventor 郝敬军钱黎明
Owner JIAXING MINHUI AUTOMOTIVE PARTS CO LTD
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