Method for improving light emitting property of LED by using laser radiated gallium nitride epitaxial wafer as substrate of LED
A technology of luminescence performance and laser irradiation, which is applied in the direction of electrical components, circuits, semiconductor devices, etc., can solve problems such as the late start of research on luminescent materials for blue LEDs, and the material performance has not reached the level expected by people, and achieves laser irradiation parameters. Accurate and controllable, significantly improved electro-optical properties, and short time period
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Embodiment 1
[0028] Cut the gallium nitride epitaxial wafer into square samples with a size of about 1cm×1cm each with a glass knife; immerse in acetone solvent for ultrasonic cleaning for 5 minutes, then rinse; immerse in alcohol solvent for ultrasonic cleaning for 5 minutes, then rinse; immerse in deionized water After ultrasonic cleaning for 10 min, rinse and dry. Put the pretreated gallium nitride epitaxial wafer on the target stage, and irradiate it with an excimer laser with a wavelength of 248nm in air, oxygen, and nitrogen environments (the air pressure is a standard atmospheric pressure); the pulse laser frequency 3Hz, single pulse energy density 0.5J / cm 2 , the number of pulses is 90. The out-of-focus amount is 4cm, and the compound eye structure is used to shape the outgoing laser light, and the spot area acting on the sample is 1cm 2, that is, a square spot with a size of 1cm×1cm. The samples obtained before and after irradiation were all deposited Ni (30nm) / Au (100nm) metal...
Embodiment 2
[0031] Cut the gallium nitride epitaxial wafer into square samples with a size of about 1cm×1cm each with a glass knife; immerse in acetone solvent for ultrasonic cleaning for 5 minutes, then rinse; immerse in alcohol solvent for ultrasonic cleaning for 5 minutes, then rinse; immerse in deionized water After ultrasonic cleaning for 10 min, rinse and dry. Place the pretreated GaN epitaxial wafer on the target stage, and irradiate it with an excimer laser with a wavelength of 248nm in an atmospheric environment; the pulse laser frequency is 3Hz, and the single pulse energy density is 0.2-0.6J / cm 2 , the number of pulses is 60, 90, 120. The out-of-focus amount is 4cm, and the compound eye structure is used to shape the outgoing laser light, and the spot area acting on the sample is 1cm 2 , that is, a square spot with a size of 1cm×1cm. After cleaning, evaporating ITO, step (mesa) lithography, ICP etching, glue removal, ITO alloy, HF acid cleaning, patterned pad lithography sp...
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