Catalytic cracking diesel fuel hydroconversion method
A technology for catalytic cracking of diesel oil and hydroconversion, which is applied in hydrotreating process, petroleum industry, treatment of hydrocarbon oil, etc., can solve the problems of accelerated carbon deposition rate of catalyst, poor quality of diesel products, affecting long-term operation, etc. Further cracking, shorter contact time, reduced effect of hydrogenation
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Embodiment 1-3
[0035] Embodiment 1-3 adopts flow process of the present invention as figure 1 .
[0036] Embodiment 1-3 In the hydrocracking reactor, three kinds of cracking catalysts of catalyst A, catalyst B and catalyst C in Table 1 are graded and loaded respectively according to the order of the catalyst bed from top to bottom. In the three examples, catalyst A The ratios of Catalyst B and Catalyst C are 1:1:1; 1:2:1 and 1:1:2, respectively.
[0037] The composition and properties of the catalyst are shown in Table 1, the properties of the raw materials used are shown in Table 2, and the reaction conditions and reaction results of Examples 1 to 3 are shown in Table 3 and Table 4 below.
Embodiment 4
[0039] use figure 2 process shown. Feedstock oil, and catalyst used are the same as embodiment 3. Wherein a gas extraction pipeline is set between the second and third cracking catalyst beds, and the others are the same as in Embodiment 3. The amount of gas phase material drawn from the gas phase extraction pipeline is 30% of the amount of circulating hydrogen.
[0040] Table 1 Composition and main properties of the cracking catalyst of the example.
[0041] project Catalyst A Catalyst B Catalyst C Chemical composition, mass% NiO 8 5 3 WO 3 24 20 18 carrier Aluminum oxide Aluminum oxide Aluminum oxide cracking components Y molecular sieve Y molecular sieve Y molecular sieve Cracking component content in the carrier, m% 80 70 60 Cracking catalyst average pore size, nm 5.0 7.0 9.0
[0042] Table 2 Raw oil properties.
[0043] Raw oil catalytic diesel Density, g / cm 3 0...
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