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Anode material for lithium-ion battery and preparation method of anode material

A technology of lithium-ion batteries and negative electrode materials, applied in battery electrodes, nanotechnology for materials and surface science, circuits, etc., can solve problems such as poor rate performance, poor structural stability, unsuitable preparation process, etc. Low cost, sufficient raw materials, good ion/electronic conduction effect

Inactive Publication Date: 2015-04-29
SOUTH CHINA UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The technical problem to be solved by the present invention is to overcome the defects of poor electrode cycle performance and rate performance caused by the poor structural stability of existing silicon-based negative electrode materials, and the preparation process is not suitable for industrial production, and to provide an amorphous silicon-tungsten carbide- Graphene composite negative electrode material and preparation method thereof

Method used

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  • Anode material for lithium-ion battery and preparation method of anode material
  • Anode material for lithium-ion battery and preparation method of anode material
  • Anode material for lithium-ion battery and preparation method of anode material

Examples

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Effect test

Embodiment 1

[0039] The WC powder with a purity of 99.9%, a particle size of 325 mesh, a purity of 99.9%, and a particle size of 1 to 2 microns is ball milled in the first step under the protection of argon; 60% of the total mass of the Si-WC composite powder; the rotational speed of the ball mill was 1000 rpm, the ball milling time was 25 hours, and the mass ratio of the stainless steel ball to the powder was 60:1 to obtain the Si-WC composite powder.

[0040] The above-mentioned Si-WC composite powder obtained through ball milling, and the graphite powder with a purity of 99.9% and a particle size of 30 to 40 microns are subjected to the second ball milling under the protection of argon; 50% of the total mass of the powder, the rotational speed of the ball mill was 1000 rpm, the ball milling time was 10 hours, and the mass ratio of the stainless steel ball to the powder was 60:1 to obtain the Si-WCG composite material.

[0041] The prepared Si-WCG composite material was uniformly mixed w...

Embodiment 2

[0043] The WC powder with a purity of 99.9%, a particle size of 325 mesh, a purity of 99.9%, and a particle size of 1 to 2 microns is ball milled in the first step under the protection of argon; 50% of the total mass of the powder; the rotational speed of the ball mill was 1000 rpm, the ball milling time was 25 hours, and the mass ratio of the stainless steel ball to the powder was 60:1 to obtain the Si-WC composite powder.

[0044]The above-mentioned Si-WC composite powder obtained through ball milling, and the graphite powder with a purity of 99.9% and a particle size of 30 to 40 microns are subjected to the second ball milling under the protection of argon; the mass of the graphite powder accounts for 50% of the total mass of the powder, the rotational speed of the ball mill was 1000 rpm, the ball milling time was 10 hours, and the mass ratio of the stainless steel ball to the powder was 60:1 to obtain the Si-WCG composite material.

[0045] The prepared Si-WCG composite ma...

Embodiment 3

[0047] The WC powder with a purity of 99.9%, a particle size of 325 mesh, a purity of 99.9%, and a particle size of 1 to 2 microns is ball milled in the first step under the protection of argon; 40% of the total mass of the Si-WC composite powder; the rotational speed of the ball mill was 1000 rpm, the ball milling time was 25 hours, and the mass ratio of the stainless steel ball to the powder was 50:1 to obtain the Si-WC composite powder.

[0048] The above-mentioned Si-WC composite powder obtained through ball milling, and the graphite powder with a purity of 99.9% and a particle size of 30 to 40 microns are subjected to the second ball milling under the protection of argon; the mass of the graphite powder accounts for 50% of the total mass of the powder, the rotational speed of the ball mill was 1000 rpm, the ball milling time was 10 hours, and the mass ratio of the stainless steel balls to the powder was 50:1 to obtain the Si-WCG composite material.

[0049] The prepared S...

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Abstract

The invention discloses an anode material for a lithium-ion battery and a preparation method of the anode material. The material is structurally characterized by adopting a core-shell structure and comprises an active and stable core formed by uniformly dispersing submicron-grade multi-scale tungsten carbide particles in an amorphous silicon substrate and a highly-conductive shell coated with a thin-layer graphene sheet formed by stripping. The preparation method is a two-step ball-milling method, during ball milling in the first step, the tungsten carbide particles can fully play a milling assisting role to efficiently refine original coarse silicon; during ball milling in the second step, the graphene sheet formed by stripping ordinary graphite can stabilize the structure and improve the electrical conductivity. Therefore, the prepared anode material for the lithium-ion battery has the advantages of stable structure, good cycle performance, excellent rate performance and the like.

Description

technical field [0001] The invention belongs to the technical field of lithium-ion batteries, and in particular relates to an amorphous silicon-tungsten carbide-graphene composite material for lithium-ion battery negative electrodes and a preparation method thereof. Background technique [0002] Lithium-ion secondary batteries have a series of significant advantages such as high working voltage, large specific capacity, long service life, and no environmental pollution, and have been widely used in various portable electronic devices. In order to meet the needs of electric vehicles, energy storage batteries, thin-film microelectronics and other fields, lithium-ion batteries must have higher capacity and energy density. As a key component of lithium-ion batteries, anode materials have an important impact on the capacity, life, safety, and cost of batteries. Therefore, the research and development of high-performance anode materials is of great significance to improve battery...

Claims

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Application Information

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IPC IPC(8): H01M4/38H01M4/62B82Y30/00B82Y40/00
CPCB82Y30/00B82Y40/00H01M4/583H01M4/625Y02E60/10
Inventor 朱敏孙威胡仁宗刘辉曾美琴刘江文
Owner SOUTH CHINA UNIV OF TECH
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