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Slurry for coating isolating membrane of lithium ion battery, isolating membrane and preparation method of slurry

A lithium-ion battery and separator technology, which is used in secondary batteries, starch coatings, battery pack components, etc. Insufficient and other problems, to achieve the effect of strong high and low temperature tolerance, uniform thickness and uniform electrical properties

Inactive Publication Date: 2014-11-12
ZHEJIANG JINMEI ENERGY SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

During the use of lithium-ion batteries, it has always been the focus of research by battery scientists to take into account the performance at high and low temperatures. Generally speaking, batteries with good performance at room temperature can only take into account good low-temperature performance or high-temperature performance, which is difficult. Achieve both high and low temperature
[0003] At present, the separators used in lithium batteries on the market are generally coated with aluminum oxide and PVDF. The high temperature resistance limit is 150 degrees Celsius, the low temperature resistance is only about zero degrees Celsius, and the high and low temperature tolerance is insufficient.

Method used

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  • Slurry for coating isolating membrane of lithium ion battery, isolating membrane and preparation method of slurry
  • Slurry for coating isolating membrane of lithium ion battery, isolating membrane and preparation method of slurry
  • Slurry for coating isolating membrane of lithium ion battery, isolating membrane and preparation method of slurry

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preparation example Construction

[0022] The present invention also provides a method for preparing the coating slurry of the separator of the lithium-ion battery with both high and low temperature, comprising the following steps:

[0023] Step 1: Mix the above-mentioned components according to the ratio of each weight percentage, and carry out planetary stirring at a speed of 80-120 RPM for 20-40 minutes.

[0024] Step 2: A high-power ultrasonic device (Guangzhou Xindongli NP8000) disperses the slurry, the power is 800-1200W, and the ultrasonic dispersion time is more than 10 minutes, that is, the coating of the separator film of the lithium-ion battery with both high and low temperature is obtained slurry.

[0025] Using the above stirring and dispersing methods and stirring parameters can improve the stirring efficiency and effectively solve the phenomenon of molecular agglomeration of the slurry.

[0026] The present invention also provides a high and low temperature separator for lithium ion batteries, i...

Embodiment 1

[0030] This embodiment provides a coating slurry for a separator of a lithium-ion battery with both high and low temperature, including the following components in weight percentage:

[0031]

[0032]

[0033] The water-based fluorine leveling agent is DuPont FS-3100, a fluorosurfactant.

[0034] The aqueous fluoride dispersion is DuPont FSWET1010, a fluorine wetting and leveling agent.

[0035] The associative thickener is Clariant thickener associative TK530.

[0036] The present invention also provides a method for preparing the coating slurry of the separator of the lithium-ion battery with both high and low temperature, comprising the following steps:

[0037] Step 1: Weigh 45kg of nano-scale aluminum oxide, 10kg of carboxylated styrene-butadiene latex, 5kg of aluminum fluoride, 3kg of methylpyrrolidone, 3kg of vinylpyrrolidone, 3kg of divinyl carbonate, 0.1kg of fluorine Surfactant DuPont FS-3100, 1kg fluorine wetting and leveling agent DuPont FSWET1010, 1kg Clar...

Embodiment 2

[0048] This embodiment provides a coating slurry for a separator of a lithium-ion battery with both high and low temperature, including the following components in weight percentage:

[0049]

[0050]

[0051] The water-based fluorine leveling agent is DuPont FS-3100, a fluorosurfactant.

[0052] The aqueous fluoride dispersion is DuPont FSWET1010, a fluorine wetting and leveling agent.

[0053] The associative thickener is Clariant thickener associative TK530.

[0054] The present invention also provides a method for preparing the coating slurry of the separator of the lithium-ion battery with both high and low temperature, comprising the following steps:

[0055] Step 1: Weigh 50kg of nano-sized aluminum oxide, 5kg of carboxylated styrene-butadiene latex, 8kg of aluminum fluoride, 2kg of methylpyrrolidone, 2kg of vinylpyrrolidone, 4kg of divinyl carbonate, 0.2kg of fluorine Surfactant DuPont FS-3100, 0.5kg fluorine wetting and leveling agent DuPont FSWET1010, 1.5kg C...

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Abstract

The invention provides slurry for coating an isolating membrane of a lithium ion battery. The slurry comprises the following components: nano-grade aluminum oxide, carboxylic butadiene-styrene latex, aluminum fluoride, N-methylpyrrolidone, vinyl pyrrolidinone, divinyl carbonate, an aqueous fluorine flatting agent, aqueous fluoride dispersing liquid, an associated thickening agent and the balance being deionized water. The invention further provides a preparation of the slurry. By virtue of combination of the components in special ratios, the slurry for coating the isolating membrane of the lithium ion battery has excellent properties of resisting high temperature up to 250 DEG C and low temperature up to -80 DEG C, and meanwhile, by virtue of spherical ultrasonic dispersion treatment used when the slurry is prepared and the special process that the basic isolating membrane is coated with the slurry, the prepared isolating membrane has the characteristics that the coating is good in molecular dispersivity, uniform in thickness and uniform in electrical property.

Description

technical field [0001] The invention relates to a coating slurry for a separator of a lithium ion battery, a separator and a preparation method thereof. Background technique [0002] Since the commercial use of lithium-ion batteries in the 1990s, they have rapidly developed due to their advantages such as high specific energy, high battery voltage, wide operating temperature range, long storage life, no memory effect, small self-discharge rate, and fast charge and discharge. Developed, at present, lithium-ion batteries have been widely used in electronic products such as mobile phones, notebook computers, digital cameras, etc., and are gradually used as power batteries in electric bicycles, model airplanes, and electric vehicles. During the use of lithium-ion batteries, it has always been the focus of research by battery scientists to take into account the performance at high and low temperatures. Generally speaking, batteries with good performance at room temperature can on...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M2/16C09D113/02C09D7/12
CPCC08K3/16C08K3/22C08K5/109C08K13/02C08K2003/164C08K2003/2227C09D103/02C09D7/61C09D7/63H01M10/0525H01M50/403H01M50/446Y02E60/10
Inventor 刘锴沈健
Owner ZHEJIANG JINMEI ENERGY SCI & TECH
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