Hot dry rock chemical fracturing fluid
A hot dry rock and fracturing fluid technology, applied in the direction of organic chemistry, chemical instruments and methods, compounds of group 5/15 elements of the periodic table, etc., can solve corrosion, affect thermal reservoir permeability, and prevent thermal reservoir Deep penetration and other issues to achieve the effect of expanding the penetration distance and improving permeability
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[0031] The preparation method of dry hot rock chemical fracturing fluid, in order of mass percentage: fluoroboric acid (HBF 4 ) 2% to 8%, polyamino polyether methylene phosphonic acid (PAPEMP) 2.5% to 10%, water 79 to 85.5% and aluminum chloride hexahydrate (AlCl 3 ·6H 2 O) 3% to 10% mixed into dry hot rock chemical fracturing fluid.
[0032] Synthesis of polyaminopolyether methylenephosphonic acid: To a four-necked flask equipped with a reflux condenser, a thermometer, a constant pressure dropping funnel and a magnetic stirrer, add 4.62 g of amino-terminated polyether (degree of polymerization n=2.6) , phosphorous acid 16.4g, deionized water 7.5ml. Add 5 mL of concentrated hydrochloric acid in multiples, 1 to 2 mL each time. Heat the oil bath to 105°C, keep stirring, and add 3g of formaldehyde solution to the flask during reflux condensation to ensure that the dropwise addition time is not less than 50min. After the dropwise addition, continue to reflux for 3.5h and distil...
Embodiment 1
[0035] In turn, 10g of HBF with a mass fraction of 40% 4 , 12.5g mass fraction is 40% PAPEMP, 72.5g water, 5g AlCl 3 ·6H 2 O solid is placed in a vessel and mixed to make a dry hot rock chemical fracturing fluid. Dissolution experiments were carried out on the tuff samples of the Yingcheng Formation in the Songliao Basin, a typical thermal reservoir of EGS. The experimental results are as follows:
[0036]
Embodiment 2
[0042] In turn, the mass fraction of 5g was 40% HBF 4 , 12.5g mass fraction of 40% PAPEMP, 77.5g water, 5g AlCl 3 ·6H 2 O solid is placed in a vessel and mixed to make a dry hot rock chemical fracturing fluid. The dissolution test was carried out on the tuff sample of the Yingcheng Formation in the Songliao Basin, a typical thermal reservoir of EGS. The reaction time was 24 hours, and the dissolution rate of the rock sample was 13.7%.
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