Nitrided silicon-vanadium-iron alloy and production method thereof
A technology of ferro-silicon-vanadium nitride and ferro-silicon-vanadium, which is applied in the field of ferroalloys, can solve the problems of many types of reaction raw materials, many types of production raw materials, and poor compositional uniformity, so as to achieve fewer types of raw materials and avoid uneven mixing , Good product quality
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Embodiment 1
[0027] Take ferrosilicon-vanadium alloy containing 30wt% vanadium and 10wt% silicon, grind it until it passes through -100 mesh, then send it into a high-temperature self-propagating reactor, and vacuumize the reactor to 10 -2 Pa, fill in high-purity nitrogen with a purity of 99.9%, ignite after the pressure in the container reaches 6MPa, keep the pressure in the container at 6-12MPa, and finish the reaction after 30 minutes, continue to fill in nitrogen to cool for 15 minutes, and then take out the furnace, take a sample to detect its composition: 25.2wt %V, 8.7wt%Si, 13.1wt%N, apparent density is 5.3g / cm 3 , the molar ratio of nitrogen to vanadium is 1.89.
Embodiment 2
[0029] Take ferrosilicon-vanadium alloy containing 45wt% vanadium and 15wt% silicon, grind it until it passes through -120 mesh, then send it into a high-temperature self-propagating reactor, and vacuumize the reactor to 10 -2 Pa, fill in high-purity nitrogen with a purity of 99.99%, ignite after the pressure in the container reaches 6MPa, keep the pressure in the container at 6-12MPa, and finish the reaction after 45min; continue to fill in nitrogen to cool for 15min and then take it out of the furnace, and take a sample to detect its composition: 35.7wt %V, 11.9wt%Si, 18.3wt%N, apparent density is 5.8g / cm 3 , the molar ratio of nitrogen to vanadium is 1.87.
Embodiment 3
[0031] Take ferrosilicon-vanadium alloy containing 60wt% vanadium and 20wt% silicon, grind it until it passes through -140 mesh, then send it into a high-temperature self-propagating reactor, and vacuumize the reactor to 10 -2 Pa, filled with high-purity nitrogen with a purity of 99.999%; ignite after the pressure in the container reaches 6MPa, keep the pressure in the container at 6-12MPa, and finish the reaction after 35 minutes, continue to fill with nitrogen to cool for 15 minutes and then take it out of the furnace, take a sample to detect its composition: 45.7wt %V, 15.6wt%Si, 23.1wt%N, apparent density is 5.4g / cm 3 , the molar ratio of nitrogen to vanadium is 1.84.
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