Method and equipment for wet recovery of waste lead paste and wet production of high-performance lead-acid battery electrode active material
A technology for waste lead-acid batteries and electrode active substances, which is applied to the wet recycling of lead or lead compounds, and the field of lead paste for waste lead-acid batteries, which can solve problems such as poor profitability, high energy consumption, and lack of competitiveness
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Embodiment 1
[0215] A process route suitable for chemical method 1 for wet recovery of waste lead paste and wet manufacturing of high-performance lead-acid battery electrode active materials, such as image 3 shown, and the equipment suitable for this chemical method 1 is as Figure 4 , 5 , 6 shown. in, Figure 4 The equipment in is composed of three main unit parts, that is, at least one reaction tank, at least one decomposition furnace, and at least one pulverizer, wherein the decomposition furnace is connected to the reaction tank and pulverizer respectively.
[0216] according to image 3 , the chemical reaction steps of this embodiment are as follows: (1) waste lead plaster reacts with sodium hydroxide to generate sodium sulfate solution and lead (hydroxide) oxide particles; Add acetic acid to the particle to form a solution, the solute in the solution is lead acetate and a small amount of lead dioxide, the soluble product generated by the reaction of lead and acetic acid; (3) mak...
Embodiment 2
[0229] A process route of chemical method 2 for wet recovery of waste lead paste and wet manufacturing of high-performance lead-acid battery electrode active materials and equipment suitable for chemical method 2 are as follows Figure 7 , 5 or 6.
[0230] according to Figure 7 , the chemical reaction steps of this embodiment are as follows: (1) waste lead plaster reacts with ammonium hydroxide to generate ammonium sulfate solution and lead (hydr) oxide particles; Nitric acid is added to the particles to form a solution, the solute in the solution is lead nitrate and a small amount of lead dioxide that may exist, and the soluble product generated by the reaction of lead and nitric acid; (3) The lead nitrate solution is reacted with ammonium carbonate to form Precipitation of solid particles and solution, wherein the main component of solid particles is lead carbonate particles, and the main component of solute in solution is ammonium nitrate; (4) Separating the solid particl...
Embodiment 3
[0239]A chemical method 3 for waste lead paste wet recovery and high-performance lead-acid battery electrode active material wet manufacturing process and equipment suitable for chemical method 3 are as follows Figure 8 , 5 or 6.
[0240] according to Figure 8 , the chemical reaction steps of this embodiment are as follows: (1) waste lead plaster reacts with sodium hydroxide to generate sodium sulfate solution and lead (hydr) oxide particles; Fluorosilicic acid is added to the particles to form a solution, the solute in the solution is lead fluorosilicate and possibly a small amount of lead dioxide, the soluble product formed by the reaction of lead and fluorosilicic acid; (3) lead fluorosilicate The solution reacts with sodium hydroxide to generate solid particle precipitation and solution, wherein the main component of the solid particle is lead hydroxide, and the main component of the solute in the solution is sodium fluorosilicate; (4) Separating the solid particle from...
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