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Metal surface polyisocyanurate modified polyurethane sandwich panel and production method thereof

A technology of polyisocyanurate and polyurethane sandwich panels, applied in the direction of metal layered products, chemical instruments and methods, layered products, etc., can solve the problems of easy shrinkage, poor flame retardant effect, low compressive strength, etc. Achieve the effects of enhanced adhesion, low thermal conductivity, and good flame retardancy

Inactive Publication Date: 2014-01-08
SHANDONG PLANT PANEL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At low density, there are mainly disadvantages such as low compressive strength, poor flame retardant effect, poor dimensional stability, easy shrinkage, and poor weather resistance.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] Preparation of combined polyether polyester polyol (white material): Accurately weigh 30g of aromatic hydrocarbon polyester polyol, 30g of sucrose initiator polyether polyol, 10g of sorbitol initiator polyether polyol, toluene di Amine starter polyether polyol 10g, glycerol polyether polyol 20g, triethanolamine crosslinking agent 4g, Demei Shichuang company's foam stabilizer L6820 and AK8805 2.5g, composite catalyst pentamethyldiethylenetriamine, N, N-dimethylcyclohexylamine, tris(dimethylaminopropyl)hexahydrotriazine, potassium oleate, potassium octanoate 1.4g, 141b foaming agent 22g, water 1g, tris(chloroisopropyl)phosphate ( TCPP) flame retardant 10g, fully stirred and mixed evenly to obtain combined polyether polyester polyol (white material).

[0032]The production of metal surface polyisocyanurate modified polyurethane (PIR) sandwich panels: the upper and lower metal panels are pressed by a molding machine, the lower panel is glued by a conventional glue dropping ...

Embodiment 2

[0034] Preparation of combined polyether polyester polyol (white material): Accurately weigh 200~400mgKOH / g aromatic hydrocarbon polyester polyol 30g, 400~500mgKOH / g aromatic hydrocarbon polyester polyol 30g sucrose starter polyether according to the proportion Polyol 20g, sorbitol starter polyether polyol 20g, triethanolamine crosslinking agent 4g, foam stabilizer L6820 and AK8805 2.5g produced by Demei Shichuang Company, composite catalyst pentamethyldiethylenetriamine, N,N- Dimethylcyclohexylamine, tris(dimethylaminopropyl)hexahydrotriazine, potassium oleate, potassium octanoate 1.6g, 141b foaming agent 22g, water 1g, tris(chloroisopropyl)phosphate (TCPP) 10g of flame retardant, fully stirred and mixed evenly to obtain combined polyether polyester polyol (white material).

[0035] Production of polyisocyanurate modified polyurethane (PIR) sandwich panels with metal surfaces: the upper and lower metal panels are pressed by a press, the lower panel is glued by a conventional ...

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Abstract

The invention relates to a metal surface polyisocyanurate modified polyurethane sandwich panel and a production method thereof. The sandwich panel is used for cold storage thermal insulation. The sandwich panel comprises an upper metal surface layer, a lower metal surface layer and a polyisocyanurate modified polyurethane foam plastic core layer. The core layer is formed by intensive mixing reaction of compound polyether polyester polyols (white material) and polyisocyanurate (black material) which are 100:100-200 by weight ratio through a high-pressure foaming machine. The compound polyether polyester polyols comprises polyhydric alcohols, foam stabilizer, catalyst, cross-linking agent, flame retardant, water and foaming agent which are 100:1-5:1-5:2-6:5-25:0.5-3:10-30 by weight ratio. The polyhydric alcohols, the catalyst, the flame retardant and the foam stabilizer are all compounded by at least two kinds. The polyisocyanurate is high-functionality polyaryl polymethylene isocyanate. The metal surface polyisocyanurate modified polyurethane sandwich panel is good in flame retardance, excellent in weather fastness and high in size stability, and B1 standards are reached totally.

Description

technical field [0001] The invention relates to a metal surface polyisocyanurate modified polyurethane (PIR) sandwich panel for cold storage heat preservation and a preparation method thereof, belonging to the field of polymer chemical materials. Background technique [0002] Polyurethane foam has small thermal conductivity, good flame retardancy, low water absorption, high compression strength, excellent mechanical properties, good electrical properties, acoustic properties, thermal insulation properties and chemical resistance, especially its thermal conductivity. The lowest among organic materials. As a kind of polyurethane building materials, polyurethane rigid foam board is easy to form, high in production efficiency, can achieve industrialization of production, standardized product specifications and sizes, construction assembly, easy to control product quality and engineering quality, and high construction efficiency. Beautiful and many other advantages, widely used i...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G18/79C08G18/48C08G18/42C08J9/14C08L75/08B32B15/095B32B5/18C08G101/00
CPCB32B15/095B32B2307/304B32B2307/3065B32B2307/734C08G18/092C08G18/4018C08G18/6622C08G2101/00C08J9/144C08J2203/142C08J2375/06C08J2375/08C08G2115/02
Inventor 郭亚莉褚建军张洪国钟东南孙志武
Owner SHANDONG PLANT PANEL
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