Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Phase change energy storage capsule and preparation method thereof

A phase-change energy storage and capsule technology, which is applied in the field of phase-change energy storage capsules and its preparation, can solve the problems of hindering the volume expansion of the core material, the phase change cannot be realized smoothly, and it is difficult to carry out actual production, so as to reduce the temperature of the wall Decrease range, increase room comfort, good elasticity

Active Publication Date: 2015-06-24
GUANGZHOU INST OF ENERGY CONVERSION - CHINESE ACAD OF SCI
View PDF10 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, these preparation methods have the following defects: 1) the use of aldehyde resins as raw materials causes environmental pollution in preparation and products, so it is difficult to carry out actual production; 2) the particle size in the phase change microcapsules is micron, and the phase change Too little transformation material leads to high supercooling, which makes it difficult for the core material to achieve phase transition at the temperature node; 3) The volume of the core material increases by about 10% when the solid-liquid phase transition occurs, while the capsule materials of phenolic and urea-formaldehyde are hard and elastic , which seriously hinders the volume expansion of the core material, resulting in the inability to realize the phase transition smoothly.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Phase change energy storage capsule and preparation method thereof
  • Phase change energy storage capsule and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] The proportion and dosage of ingredients are: 100kg of normal temperature phase change energy storage material; 50kg of styrene-butadiene latex; 10kg of 10% NF (naphthalenesulfonic acid formaldehyde condensate sodium salt); 5kg of 10% ammonium persulfate solution; 6kg of 5% aluminum sulfate solution; Zinc oxide, stearic acid, deionized water, 27kg of slurry mixed according to the mass ratio of 3:1:4, referred to as zinc grease slurry; starch 2kg.

[0026] (1) Take the phase change energy storage material at room temperature, process it into 2-5mm particles with a screw extruder, and store it below 20°C for later use.

[0027] (2) Add styrene-butadiene latex to the reaction kettle, add NF, ammonium persulfate solution, and zinc fat slurry, adjust the speed to 200rpm, and stir for 30min.

[0028] (3) Add phase change energy storage particles, adjust the temperature to 20-23°C, adjust the speed to 100rpm, spray the aluminum sulfate solution, stir for 15 minutes, spray the ...

Embodiment 2

[0032] The proportion and dosage of ingredients are: 120kg of normal temperature phase change energy storage material; 50kg of styrene-butadiene latex; 2.5kg of 40% sodium dodecylbenzenesulfonate; 2.5kg of 20% ammonium persulfate solution; , stearic acid, deionized water, 21kg of slurry mixed according to the mass ratio of 3:1:3, referred to as zinc lipid slurry; starch 2kg.

[0033] 1. Take the phase change energy storage material at room temperature, process it into 2-5mm particles with a screw extruder, and store it below 20°C for later use.

[0034] 2. Add styrene-butadiene latex to the reaction kettle, add sodium dodecylbenzenesulfonate, ammonium persulfate, and zinc grease slurry, adjust the speed to 200rpm, and stir for 30min.

[0035] 3. Add phase change energy storage particles, adjust the temperature to 20-23°C, adjust the speed to 100rpm, spray the aluminum sulfate solution, stir for 15 minutes, spray the aluminum sulfate solution, continue stirring for 30 minutes, ...

Embodiment 3

[0039] The proportion and dosage of ingredients are: 140kg of normal temperature phase change energy storage material; 40kg of epoxy rubber latex; 2kg of 40% sodium dodecylbenzenesulfonate; 2kg of 30% hydrogen peroxide solution; 2kg of 20% aluminum sulfate solution; , stearic acid, deionized water, 12kg of slurry mixed according to the mass ratio of 3:1:3, referred to as zinc lipid slurry; starch 2kg.

[0040] 1. Take the phase change energy storage material at room temperature, process it into 2-5mm particles with a screw extruder, and store it below 20°C for later use.

[0041] 2. Add epoxidized rubber latex to the reaction kettle, add NF, hydrogen peroxide, and zinc grease slurry, adjust the speed to 200rpm, and stir for 30min.

[0042] 3. Add phase change energy storage particles, adjust the temperature to 20-23°C, adjust the speed to 100rpm, spray the aluminum sulfate solution, stir for 15 minutes, spray the aluminum sulfate solution, continue stirring for 30 minutes, spr...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
particle diameteraaaaaaaaaa
phase transition temperatureaaaaaaaaaa
phase transition temperatureaaaaaaaaaa
Login to View More

Abstract

The invention provides a phase change energy storage capsule and a preparation method thereof. The capsule is formed by the interface polymerization of a polar latex and a normal-temperature (25-28DEG C) phase change material particle surface prepared in advance under the action of an additive, so the phase change material is still wrapped in the capsule after the phase change material is molten after the temperature is higher than the phase change temperature of the phase change material, and does not overflow in all directions. The normal-temperature phase change energy storage capsule prepared through the method can be combined with a building wall, and gives the temperature adjustment function to the wall through the latent heat absorption and release characteristics of the phase change material when the temperature difference between day and night is large. The phase change energy storage capsule is prepared through molding a core material and then wrapping with a wall material, so compared with other kinds of phase change capsules, the phase change energy storage capsule has the following advantages: 1, the core material is wrapped by the film of the latex, so formaldehyde and other volatile monomer substances are not contained, and the capsule is environmentally-friendly and has no pollution; 2, the particle of the capsule is in millimeter level, so the unit capacity of the core material is large, and the capsule has no super-cooling phenomenon; and 3, the flexibility of the wall material is good, so the volume of the capsule can be expanded with the liquefaction of the core material.

Description

technical field [0001] The invention relates to a building energy-saving material, in particular to a phase change energy storage capsule and a preparation method thereof. technical background [0002] The energy storage material containing phase change material (PCM) uses the temperature difference between day and night of the environment and the absorption and release of phase change latent heat to adjust the indoor air temperature, reduce the indoor temperature rise, and reduce the energy consumption of air conditioning equipment that adjusts the indoor temperature. It is an important measure of building energy saving and also the mainstream development trend in the field of building materials. Some researchers estimate that if building materials containing phase change materials can be widely used in buildings, the electricity consumption for heating and cooling of buildings can be reduced by 50%. [0003] At present, the phase change materials used in building material...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C09K5/06B01J13/16
Inventor 黎涛冯自平于亮宋文吉张建军
Owner GUANGZHOU INST OF ENERGY CONVERSION - CHINESE ACAD OF SCI
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products