Toner composition containing spacer particles treated with charge control agent
A technology of charge control agent and spacer particles, which is applied in the field of toner, and can solve problems such as increasing problems and reducing printing life
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Embodiment 1
[0136] The charge control agent-treated spacer particles are formed as follows. 3% of alkyltrialkoxysilane spacer particles having the following general formula with an average particle size or diameter of 500 nm
[0137]
[0138] Place in a 1% solution of 3,5-di-tert-butyl aluminum salicylate and mix until completely dispersed. The treated spacer particles are dried, for example, by oven, rotary evaporator, freeze dryer or other drying methods. As a result, charge control agent-treated spacer particles containing alkyltrialkoxysilane spacer particles having 3,5-di-t-butylaluminum salicylate charge control agent particles on the surface of the silane particles were obtained.
Embodiment 2
[0140] A toner containing spacer particles treated with a charge control agent is prepared as follows. The particles of Example 1 were predispersed in deionized water containing 1.5% sodium lauryl sulfate surfactant. Emulsion / aggregate particles were first prepared by homogenizing styrene / butyl acrylate resin latex with pigment dispersion, paraffin wax dispersion and polyaluminum chloride (PAC) at about 20-30°C. The mixture is then heated with mixing to a temperature slightly below the Tg of the resin (45-65°C) to grow the particle nuclei to the desired size (4.8-5.8um). Subsequent shell addition and proper particle size (depending on target final particle size) is achieved. 3 / 4 of the shells were added, followed by 1 / 4 of the shells containing the treated spacer particles of Example 1. To prevent further growth of the particles after addition of the shell, sodium hydroxide solution was added and the temperature in the reactor was increased to obtain coalescence. At a circu...
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