Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Preparation method of denitration catalyst with nanoscale ordered honeycomb structure

一种脱硝催化剂、蜂窝结构的技术，应用在化学仪器和方法、物理/化学过程催化剂、分离方法等方向，能够解决孔易阻塞、内表面不能充分利用、传质效率不高等问题，达到提高抗硫性能的效果

Active Publication Date: 2015-02-25
SHANGHAI UNIV
View PDF3 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, mesoporous materials have small pore size, the inner surface cannot be fully utilized in the process of air conduction, the mass transfer efficiency is not high, and the pores are easily blocked, which limits its practical application.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Preparation method of denitration catalyst with nanoscale ordered honeycomb structure
  • Preparation method of denitration catalyst with nanoscale ordered honeycomb structure

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] The preparation of catalyst: get styrene monomer and methacrylic acid, sodium bicarbonate and deionized water, after mixing with the mass ratio of 9:0.5:0.24:85, add the ammonium persulfate that massfraction is 0.3% in mixture as Initiator, under nitrogen protection, 85 o C, reacted under stirring conditions for 12h. The reaction products were subjected to evaporative self-assembly after centrifugal washing to prepare polystyrene templates. Cerium oxalate and zirconium silicate with a molar ratio of 8:2 are fully dissolved in a mixed solution of water, citric acid, and ethylene glycol with a mass ratio of 10:5:3, and then adsorbed by a polystyrene template and dried. The product was subsequently treated with 6 o C / min rate heating up to 350 o C, calcined for 2 h, then heated to 750 o C, calcination for 5 h to obtain an ordered honeycomb framework of cerium-zirconium oxide. Disperse it with sodium tungstate at a mass ratio of 20:1 in deionized water, and evaporate t...

Embodiment 2

[0029] The preparation of catalyst: get styrene monomer and methacrylic acid, after sodium bicarbonate and deionized water are mixed by the mass ratio of 10:1:0.24:85, add the ammonium persulfate that massfraction is 0.4% in the mixture as triggering agent, under nitrogen protection, 80 o C, reacted under stirring conditions for 10h. The reaction products were subjected to evaporative self-assembly after centrifugal washing to prepare polystyrene templates. Cerium carbonate and zirconium nitrate with a molar ratio of 7:3 were fully dissolved in a mixed solution of water, citric acid, and ethylene glycol with a mass ratio of 10:5:3, and then adsorbed by a polystyrene template and dried. The product was subsequently treated with 4 o C / min rate of heating up to 350 o C, calcined for 1.5 h, then heated to 650 o C, calcination for 4 h to obtain nanoscale ordered honeycomb framework of cerium-zirconium oxide. Disperse it and tungsten chloride in deionized water at a mass ratio ...

Embodiment 3

[0032] The preparation of catalyst: get styrene monomer and methacrylic acid, sodium bicarbonate and deionized water, after mixing by the mass ratio of 11:2:0.24:85, add the benzyl peroxide that massfraction is 0.5% in mixture Acyl as initiator, under nitrogen protection, 75 o C, reacted for 8h under stirring conditions. The reaction products were subjected to evaporative self-assembly after centrifugal washing to prepare polystyrene templates. After cerium nitrate and zirconium oxychloride with a molar ratio of 6:4 are fully dissolved in a mixed solution of water, citric acid, and ethylene glycol with a mass ratio of 10:5:3, they are adsorbed by a polystyrene template and dried. The product was subsequently treated with 2 o C / min rate of heating up to 350 o C, calcined for 2 h, then heated to 550 o C, performing a calcination treatment for 3 hours to obtain an ordered honeycomb framework of cerium-zirconium oxide. Disperse it and phosphotungstic acid in deionized water a...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention relates to a preparation method of a denitration catalyst with a nanoscale ordered honeycomb structure cerium-zirconium oxide skeleton and dispersed tungsten oxide loaded on the surface, belonging to the technical field of preparation technologies of nanometer materials and environment protection. The preparation method is characterized by comprising the following steps of: depositing polrvinyl benzene microspheres into an ordered template, absorbing metal salt solution of cerium and zirconium under the condition that citric acid is taken as a complexing agent, calcining step by step to obtain the catalyst skeleton, and loading tungsten on the surface of the catalyst by means of impregnation and calcined activation to obtain the denitration catalyst with the characteristics. Due to the joint action of the structure and the surface load of the tungsten oxide, the catalyst is provided with a wide catalysis temperature window. Therefore, the catalyst provided by the invention can be used for selective catalytic reduction of nitric oxide in tail gas of a diesel engine and in smoke discharged out of a coal-fired power plant, a steel mill, etc.

Description

technical field [0001] The invention relates to a preparation method of a denitration catalyst with a nano-scale ordered honeycomb structure, which belongs to the technical field of nano-material preparation technology and environmental protection. Background technique [0002] Nitrogen oxides (NO x ) mainly to NO and NO 2 It is often found in the flue gas emitted by diesel engines and fossil fuel combustion. Because it can lead to the formation of acid rain and photochemical smog, which causes great damage to the living environment of human beings, it is regarded as a serious air pollutant. . At present, NO in flue gas and diesel engine exhaust produced by stationary sources such as thermal power plants and boiler combustion x The removal is mainly accomplished by two methods: dry method and wet method. The wet method includes several methods such as direct absorption method, oxidation absorption method and reduction absorption method, while the dry method includes catal...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): B01J23/30B01J35/04B01D53/86B01D53/56
Inventor 张登松施利毅蔡思翔李红蕊黄垒张剑平
Owner SHANGHAI UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com