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A membrane device for catalytic gasoline desulfurization and refining

A catalytic gasoline and membrane device technology, which is applied in the fields of refined hydrocarbon oil and petroleum industry, can solve the problems of gasoline octane loss, difficulty in removal, high equipment investment and operating costs, and achieve less octane loss and process equipment Simple, easy to enlarge and expand the effect

Active Publication Date: 2014-10-22
NINGXIA BAOTA PETROCHEM GROUP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Hydrodesulfurization is a relatively mature and commonly used desulfurization refining method at present. This method can effectively remove inorganic sulfur and simple organic sulfur compounds, but it is difficult to remove fused-ring thiophene sulfur-containing compounds and their derivatives. Moreover, harsh conditions such as high temperature, high pressure, hydrogen environment and precious metal catalysts are required, and equipment investment and operating costs are relatively high, which will also cause a large loss of gasoline octane number during desulfurization.

Method used

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  • A membrane device for catalytic gasoline desulfurization and refining

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Effect test

Embodiment 1

[0016] FCC gasoline with a sulfur content of 500-800μg / g is used as raw material, the feed flow rate is 15L / h, and the raw material is heated to 105-115°C to enter the membrane system. The effective membrane area of ​​each stage of the two-stage membrane separation system is 1m 2 After being treated by the device, the sulfur content of the FCC gasoline can be reduced to 50-100 μg / g, and the octane number loss of the FCC gasoline after desulfurization is below 1%.

Embodiment 2

[0018] FCC gasoline with a sulfur content of 800-1100μg / g is used as raw material, the feed flow rate is 15L / h, and the raw material is heated to 105-115°C to enter the membrane system. The effective membrane area of ​​each stage of the two-stage membrane separation system is 1m 2 After being treated by the device, the sulfur content of the FCC gasoline can be reduced to 150-400 μg / g, and the octane number loss of the FCC gasoline after desulfurization is 1-1.5%.

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Abstract

The invention relates to membrane device for desulfurizing and refining catalytic gasoline. The membrane device mainly comprises a raw material tank, a feed pump, a bag-type filter, a preheater, a first-grade membrane separating system, a second-grade separating system, a cooler, a micro-filtration membrane filter, a refined oil storage tank, a condensing tower, a buffer tank, a vacuum pump, a recovery tower and a high-sulfur rich-impurity oil tank, wherein a lower portion of the raw material tank is connected with an inlet of the feed pump, an outlet of the feed pump is connected with an inlet of the bag-type filter, an outlet of the bag-type filter is connected with an inlet of the preheater, an outlet of the preheater is connected with a feed inlet of the first-grade membrane separating system, a purified oil outlet of the first-grade membrane separating system is connected with a feed inlet of the second-grade separating system, a purified oil outlet of the second-grade separating system is connected with an inlet of the cooler, an outlet of the cooler is connected with an inlet of the micro-filtration membrane filter, an outlet of the micro-filtration membrane filter is connected with the refined oil storage tank, an outlet of the condensing tower is connected with the buffer tank which is connected with an air inlet of the vacuum pump, an air outlet of the vacuum pump is connected with the recovery tower, and an outlet of the recovery tower is communicated with the atmosphere.

Description

technical field [0001] The invention belongs to the technical field of refining oil products in the petroleum refining industry, and relates to a membrane device for catalytic gasoline desulfurization and refining. Background technique [0002] The processing volume of high-sulfur crude oil in my country is increasing year by year, heavy oil catalytic cracking has been popularized, catalytic gasoline accounts for more than 85% of finished gasoline, and the sulfur contained in catalytic gasoline accounts for about 90%-98% of the total sulfur content of gasoline. Active thiols and inactive disulfides, thioethers, thiophenes, benzothiophenes and their derivatives exist. Therefore, it has become an urgent task for my country's oil refining industry to carry out extensive research on FCC gasoline desulfurization and refining technology to reduce the sulfur content in FCC gasoline. Hydrodesulfurization is a relatively mature and commonly used desulfurization refining method at pre...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G31/00
Inventor 张立忠吕林昌任立广杨惠琳韩彩琴杨晓丽
Owner NINGXIA BAOTA PETROCHEM GROUP
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