Forward osmosis membrane having high flux for removing salt from sea water and manufacturing method threrof
一种正渗透膜、脱盐的技术,应用在用于海水脱盐的正渗透膜及其制备领域,能够解决减少寿命、分离功能损失等问题,达到防止反向扩散、提高渗水性和水通量、保证耐污染性和化学品耐受性的效果
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[0121] The invention provides a method for preparing the forward osmosis membrane used for seawater desalination according to the invention.
[0122] More specifically, a method for preparing a forward osmosis membrane for desalination of seawater is provided, the membrane has a three-layer structure of a nonwoven fabric layer, a hydrophilic polymer layer and a polyamide layer, the method comprising: ( a) forming a hydrophilic polymer layer by coating a solution containing 10 to 25% by weight of a hydrophilic polymer on a nonwoven fabric layer; and (b) forming an organic solution containing a polyfunctional acid halide compound with An aqueous solution containing a polyfunctional amine or an alkylated aliphatic amine is contacted on the hydrophilic polymer layer to perform interfacial polymerization to form the polyamide layer.
[0123]Also provided is a method for preparing a forward osmosis membrane used for seawater desalination, the membrane has a two-layer structure of a ...
Embodiment 1
[0149] A solution containing 17.5 wt% of polyacrylonitrile as a hydrophilic polymer in an organic solvent was cast on a glass plate at a thickness of 50 μm, and then phase-transferred in water used as a non-solvent at room temperature to form a hydrophilic permanent polymer layer. The hydrophilic polymer layer thus obtained was kept in ultrapure water for about one day to extract the solvent. On the surface of the solvent-extracted membrane, an aqueous solution containing 2 wt % m-phenylenediamine (MPD) was interfaced with an organic solution containing 0.1 wt % trimesoyl chloride (TMC) in ISOPAR solvent (Exxon Corp.) In contact, the polyamide layer is formed through the polymerization reaction between these compounds to complete the composite membrane.
Embodiment 2、3 and 4
[0151] These procedures were carried out in the same manner as described in Example 1, except for the membrane composition as given in Table 1, to prepare composite membranes.
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