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Strippable semi-conductive shielding material for ethylene propylene rubber cable

An ethylene-propylene rubber, semi-conductive technology, applied in the direction of insulated cables, cables, conductors, etc., can solve the problems that the ethylene-propylene insulating layer cannot be vulcanized simultaneously, the adhesive force of the ethylene-propylene insulating layer is insufficient, and the volume resistance of the shielding material is high. Uniform mixing, solving poor extrusion process performance and good extrusion processing performance

Inactive Publication Date: 2012-07-11
重庆鸽牌电线电缆有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The technical problem to be solved by the present invention is that when EVA is used as the base material, the volume resistance of the shielding material is too high, the adhesion force with the ethylene-propylene insulating layer is not enough, it is not easy to peel off, and the ethylene-propylene insulating layer cannot be vulcanized synchronously, resulting in delamination or blistering. To solve the technical defects of ethylene-propylene rubber cables, provide a peelable semi-conductive shielding material for ethylene-propylene rubber cables with good semi-conductivity, moderate adhesion to the insulating layer, easy peeling, and vulcanization speed equivalent to that of ethylene-propylene rubber.

Method used

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  • Strippable semi-conductive shielding material for ethylene propylene rubber cable
  • Strippable semi-conductive shielding material for ethylene propylene rubber cable
  • Strippable semi-conductive shielding material for ethylene propylene rubber cable

Examples

Experimental program
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Effect test

Embodiment 1

[0032] A strippable semi-conductive shielding material for ethylene-propylene rubber cables, composed of the following raw materials in parts by weight: 70 parts of ethylene vinyl acetate, 30 parts of chlorinated polyethylene, 55 parts of conductive carbon black, and 10 parts of coarse particle carbon black , 8 parts of metal oxide, 30 parts of mineral filler, 3 parts of dispersant, 2 parts of cross-linking agent, 4 parts of auxiliary cross-linking agent, 2 parts of anti-aging agent, 15 parts of plasticizer. The content of vinyl acetate in the selected ethylene vinyl acetate is 50%, the metal oxide is light magnesium oxide, the mineral filling is light calcium carbonate, the dispersant is polyethylene wax, and the crosslinking agent is diisopropyl peroxide. Benzene, trimethylolpropane triacrylate as co-crosslinking agent, 2,2,4-trimethyl-1,2-dihydroquinoline polymer as anti-aging agent, dioctyl sebacate as plasticizer .

[0033] The strippable semi-conductive shielding compou...

Embodiment 2

[0045] A strippable semi-conductive shielding material for ethylene-propylene rubber cables, composed of the following raw materials in parts by weight: 70 parts of ethylene vinyl acetate, 30 parts of chlorinated polyethylene, 50 parts of conductive carbon black, and 5 parts of coarse particle carbon black , 5 parts of metal oxide, 20 parts of mineral filler, 5 parts of dispersant, 3 parts of cross-linking agent, 4 parts of auxiliary cross-linking agent, 3 parts of anti-aging agent, 15 parts of plasticizer. The content of vinyl acetate in the selected ethylene vinyl acetate is 50%, the metal oxide is light magnesium oxide, the mineral filling is light calcium carbonate, the dispersant is polyethylene wax, and the crosslinking agent is diisopropyl peroxide. Benzene, trimethylolpropane triacrylate as co-crosslinking agent, 2,2,4-trimethyl-1,2-dihydroquinoline polymer as anti-aging agent, dioctyl phthalate as plasticizer ester.

[0046] Wherein, the stripped semi-conductive shie...

Embodiment 3

[0049] A peelable semi-conductive shielding material for ethylene-propylene rubber cables, which is composed of the following raw materials in parts by weight: 70 parts of ethylene vinyl acetate, 30 parts of chlorinated polyethylene, 65 parts of conductive carbon black, and 10 parts of coarse particle carbon black , 7 parts of metal oxide, 30 parts of mineral filler, 10 parts of dispersant, 4 parts of crosslinking agent, 5 parts of co-crosslinking agent, 4 parts of anti-aging agent, 17 parts of plasticizer. The content of vinyl acetate in the selected ethylene vinyl acetate is 50%, the metal oxide is light magnesium oxide, the mineral filling is modified kaolin, the dispersant is stearic acid, and the crosslinking agent is dicumyl peroxide The auxiliary cross-linking agent is trimethylolpropane triacrylate, the anti-aging agent is 2,2,4-trimethyl-1,2-dihydroquinoline polymer, and the plasticizer is dibutyl phthalate .

[0050] Wherein, the stripped semi-conductive shielding m...

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Abstract

The invention discloses a strippable semi-conductive shielding material for an ethylene propylene rubber cable. The shielding material is prepared by mixing the following raw materials in part by weight: 70 parts of ethylene vinyl acetate, 30 parts of chlorinated polyethylene, 50 to 70 parts of conductive carbon black, 5 to 15 parts of coarse-particle carbon black, 5 to 10 parts of metal oxide, 20 to 40 parts of mineral filler, 3 to 20 parts of dispersing agent, 2 to 6 parts of cross-linking agent, 4 to 6 parts of cross-linking aid, 2 to 5 parts of anti-ageing agent and 15 to 20 parts of plasticizer. The defects that the shielding material has overhigh volume resistivity, and insufficient adhesion with an ethylene propylene insulation layer, and is difficult to strip, the shielding material and the ethylene propylene insulation layer cannot be synchronously vulcanized, and the like in the prior art are overcome, and the strippable semi-conductive shielding material for the ethylene propylene rubber cable has high semi-conductivity, high extrusion processability, and moderate adhesion with the insulation layer, is easy to strip and has a vulcanization rate equivalent to that of ethylene propylene rubber.

Description

technical field [0001] The invention belongs to the field of composite materials, and in particular relates to a peelable semiconductive shielding material for ethylene-propylene rubber cables. Background technique [0002] Power cable semi-conductive shielding material prevents partial discharge by uniform electric field distribution in the insulating layer, improves the electric strength of the cable, and improves the service life of the cable. Semi-conductive shielding materials for ethylene-propylene rubber cables are widely used in mining medium-voltage rubber-sheathed cables, marine cables, and medium-voltage rubber-sheathed power cables. [0003] To make the shielding material semi-conductive, a large amount of semi-conductive carbon black should be added to the base material. In the early days, ethylene-propylene rubber, chlorinated polyethylene, and natural styrene-butadiene rubber were used as base materials. The above-mentioned materials have high molecular weigh...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/08C08L31/04C08L23/28H01B7/17C08K13/02C08K3/04C08K3/22B29B7/28B29B7/72
Inventor 张涛张敏
Owner 重庆鸽牌电线电缆有限公司
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