Europium ion-doped aluminum magnesium phosphate blue phosphor and preparation method thereof
A blue phosphor, aluminum magnesium phosphate technology, applied in the field of fluorescent materials, to achieve the effect of high-efficiency response characteristics, cost reduction, and wide emission band
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Embodiment 1
[0018] (1) According to Mg ion: Eu ion: AlPO 4 The molar ratio is 0.999:0.001:1, take MgO, AlPO 4 、Eu 2 o 3 , to mix;
[0019] (2) Heat the mixture obtained in step (1) to 1400°C, keep it warm for 0.5 hours, and then cool it naturally;
[0020] (3) Place the mixture obtained in step (2) in an environment of CO reducing gas, and keep it warm for 0.5 hours at 1300 ° C. After natural cooling, the chemical composition formula is Mg 0.999 Eu 0.001 (AlPO 4 ) O Europium ion-doped magnesium aluminum phosphate phosphor.
Embodiment 2
[0022] (1) According to Mg ion: Eu ion: AlPO 4 The molar ratio is 0.98:0.02:0.9, take MgCO 3 , AlPO 4 、Eu 2 o 3 , to mix;
[0023] (2) Heat the mixture obtained in step (1) to 1300°C, keep it warm for 2 hours, and then cool it naturally;
[0024] (3) Place the mixture obtained in step (2) in H 2 +N 2 Under the environment of reducing gas, keep warm at 1200°C for 1 hour, and after natural cooling, the chemical composition formula is Mg 0.98 Eu 0.02 (AlPO 4 ) 0.9 O Europium ion-doped magnesium aluminum phosphate phosphor.
Embodiment 3
[0026] (1) According to Mg ion: Eu ion: AlPO 4 The molar ratio is 0.95:0.05:1.2, take Mg(HCO 3 )OH, AlPO 4 、Eu 2 o 3 , to mix;
[0027] (2) Place the mixture obtained in step (1) in an environment of CO reducing gas, raise the temperature to 1300°C, keep it warm for 2 hours, and after natural cooling, the chemical composition formula is Mg 0.95 Eu 0.05 (AlPO 4 ) 1.2 O Europium ion-doped magnesium aluminum phosphate phosphor.
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