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Bioaugmentation treatment technology of high ammonia nitrogen wastewater

A bio-enhancement and treatment process technology, applied in the field of water treatment, can solve the problems that affect the stable operation of the system and the effluent quality, increase the capital construction investment and operating costs, and the total hydraulic retention time of the system, etc. , the effect of increasing the volume load

Inactive Publication Date: 2011-02-16
SHANGHAI HONESS ENVIRONMENTAL TECH CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the traditional biological denitrification process such as A / O method, A 2 / O method, etc., still have the following problems: ①The nitrifying bacteria group is difficult to maintain a high biological concentration due to the slow proliferation rate, so the total hydraulic retention time of the system is longer, the load is lower, and the infrastructure investment and operating costs are increased; ②The impact resistance is weak. When the influent water quality changes greatly, the operation of the system will be seriously affected
③The ability to treat high ammonia nitrogen water is poor. When the concentration of ammonia nitrogen in the biochemical system is higher than 500mg / L, it will seriously inhibit microorganisms, which will affect the stable operation of the system and the quality of effluent water

Method used

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  • Bioaugmentation treatment technology of high ammonia nitrogen wastewater
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Examples

Experimental program
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Effect test

Embodiment 1

[0027] Example 1, using the present invention to treat wastewater from a saccharin factory, using a combined process of primary anoxic pool + tertiary aerobic filter + membrane pool, the enzyme floating filler used is enzyme floating A series of ionic enzymatic suspension fillers. Influent COD Cr The concentration is 2000-13000mg / L, NH 3 -N concentration is 1000-5500mg / L, anoxic tank temperature is 28-32℃, aerobic filter temperature is 25-30℃, total hydraulic retention time is 120h, no need to add carbon source, but only need to add about 180mg / L alkali degree (as CaCO 3 count), effluent COD Cr The concentration is 20-300mg / L, NH 3 -N concentration is 0.65-30mg / L. COD Cr The average removal rate is above 90%, NH 3 The average removal rate of -N is above 99%.

Embodiment 2

[0028] Example 2, using the present invention to treat wastewater from chemical fertilizer plants, using a combined process of one-stage anoxic pool + two-stage aerobic filter + membrane pool, and the enzyme floating filler used is enzyme floating A series of ionic enzymatic suspension fillers. Influent COD Cr The concentration is 300-700mg / L, NH 3 -N concentration is 200-400mg / L, anoxic pool temperature is 30-35℃, aerobic filter temperature is 20-30℃, total hydraulic retention time is 72h, only need to add about 200mg / L methanol as carbon source, effluent COD Cr The concentration is 10-50mg / L, NH 3 -N concentration is 0.10-2.0mg / L. COD Cr The average removal rate is above 90%, NH 3 The average removal rate of -N is above 99%.

Embodiment 3

[0029] Example 3, using the present invention to treat wastewater from a coking plant, using a combined process of primary anoxic pool + tertiary aerobic filter + membrane pool, the enzyme floating filler used is enzyme floating A series of ionic enzymatic suspension fillers. Influent COD Cr The concentration is 2500-5500mg / L, NH 3-N concentration is 300-600mg / L, anoxic tank temperature is 30-35°C, aerobic filter temperature is 25-30°C, total hydraulic retention time is 64h, effluent COD Cr The concentration is 40-150mg / L, NH 3 -N concentration is 0.20-4.0mg / L. COD Cr The average removal rate is above 90%, NH 3 The average removal rate of -N is above 99%.

[0030] It can be seen from the above examples that the present invention has good removal effects on different types of high ammonia nitrogen wastewater.

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Abstract

The invention relates to a bioaugmentation treatment technology of the high ammonia nitrogen wastewater. The treatment technology is characterized in that under the condition that dissolved oxygen exists in the high ammonia nitrogen wastewater, an aerobic pool, an aerobic filter and a membrane pool are established, wherein by utilizing the metabolism of the aerobic microorganism, high concentration of organic substances are degraded, the organic substances with high molecular weight and energy are converted to substances with low molecular weight and energy; the aerobic pool adopts internal circulation and large-scale external circulation hydraulic agitation; and the aerobic filter is filled with novel fixed enzyme-floating filler and immobilized microorganism and microporous aeration and jet aeration are combined for aeration, thus the flow pattern of the nitrification filter is improved. Compared with the prior art, the system of the invention has high sludge concentration and the corresponding volume loading is also high, thus the floor space is small and the capital cost is low; the conversion rate and utilization rate of atmospheric oxygen is high, the effect of mass transfer is good, the anti-shock loading capability of the system is high, the effluent quality is stable; the operating cost is low; the density is increased relatively, the solid-liquid separating effect is good and the yield of excess sludge is low.

Description

technical field [0001] The invention relates to a high-ammonia-nitrogen wastewater treatment process, which belongs to the technical field of water treatment, and in particular to a biointensified treatment process for high-ammonia-nitrogen wastewater. Background technique [0002] In recent years, industries such as coking, pesticides, fertilizers, chemicals, and rare earth smelting have developed rapidly, and a large amount of high-concentration ammonia nitrogen wastewater has been discharged accordingly. The discharge of a large amount of ammonia nitrogen into the water body will lead to eutrophication of the water body. The eutrophication of the water body will not only reduce the dissolved oxygen in the water, destroy the original natural ecological environment of the water body, but also affect the water safety and sanitation of the water source, and lose the original quality of the water body. Function. For urban sewage treatment plants, the discharge of high-ammonia...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/14
Inventor 王文标张宝王浩李继香毛勇先高永军张艳周欣赵云翔张雷
Owner SHANGHAI HONESS ENVIRONMENTAL TECH CORP
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