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Foamed micropore layer of artificial leather for lining of PE shoes and method for preparing artificial leather by using same

A technology of artificial leather and microporous layer, which is applied in the field of artificial leather to achieve the effect of high foaming ratio, low stiffness and high stiffness

Inactive Publication Date: 2010-08-18
袁飞
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Aiming at the various shortcomings of the raw material formula of the foamed microporous layer used in artificial leather and the production process of artificial leather to a certain extent, the inventor has successfully developed a PE-shoe lining artificial leather foamed microporous layer after long-term experimental research. The raw material formula of the foamed microporous layer can be used to produce a kind of artificial leather with the advantages of high stiffness, good cold resistance, high foaming ratio, and vulcanization resistance.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0060] The raw material ratio of PE-shoe lining artificial leather foamed microporous layer of the present invention: expressed in parts by weight, 100 parts of polyethylene PE, 28 parts of ethylene-vinyl acetate copolymer EVA, 55 parts of styrene-butadiene copolymer SBS , active CaCO 3 85 parts, 6 parts of azodicarbonamide Ac, 3 parts of zinc oxide ZnO, 2 parts of titanium dioxide, 3 parts of dicumyl peroxide DCP and 1.8 parts of antioxidant (1.8 parts of antioxidant is made of thiodipropyl Dilauryl acid DLTP 0.5 parts, antioxidant 10100.5 parts and antioxidant 2640.8 parts).

[0061] Active CaCO used in the raw material of PE-shoe lining artificial leather foaming microporous layer of the present invention 3 The fineness is 200-500 mesh.

[0062] Active CaCO 3 The treatment method of this method: prepare light calcium carbonate and titanate coupling agent (3-aminopropyltrimethoxysilane) in a ratio of 100:0.3 by weight, add it to a high-speed mixer, and heat it at a temper...

Embodiment 2

[0069] Embodiment 2: basically the same as Embodiment 1, the difference is:

[0070] The raw material ratio of PE-shoe lining artificial leather foamed microporous layer of the present invention: expressed in parts by weight, 100 parts of polyethylene PE, 30 parts of ethylene-vinyl acetate copolymer EVA, 53 parts of styrene-butadiene copolymer SBS , active CaCO 3 90 parts, 6.5 parts of azodicarbonamide Ac, 3 parts of zinc oxide ZnO, 2 parts of titanium dioxide, 3 parts of dicumyl peroxide DCP and 1.8 parts of antioxidant (1.8 parts of antioxidant is made of thiodipropyl 0.5 part of dilauryl DLTP, 0.5 part of antioxidant 1010 and 2640.8 parts of antioxidant).

[0071] Active CaCO 3 The treatment method: light calcium carbonate and titanate coupling agent (3-aminopropyltriethoxysilane) are prepared in a ratio of 100:0.5 by weight, and added to a high-speed mixer, at a temperature of Mix at 60°C for 30 minutes at a speed of 2000r / min. After mixing, it becomes active light calc...

Embodiment 3

[0077] Embodiment 3: basically the same as Embodiment 1, the difference is:

[0078] The raw material ratio of PE-shoe lining artificial leather foamed microporous layer of the present invention: expressed in parts by weight, 100 parts of polyethylene PE, 26 parts of ethylene-vinyl acetate copolymer EVA, 53 parts of styrene-butadiene copolymer SBS , active CaCO 3 80 parts, 6 parts of azodicarbonamide Ac, 3 parts of zinc oxide ZnO, 2 parts of titanium dioxide, 3 parts of dicumyl peroxide DCP and 1.8 parts of antioxidant (1.8 parts of antioxidant is made of thiodipropyl 0.5 part of dilauryl DLTP, 0.5 part of antioxidant 1010 and 2640.8 parts of antioxidant).

[0079] Active CaCO 3 The treatment method: prepare light calcium carbonate and titanate coupling agent (vinyl triethoxysilane) at a ratio of 100:0.1 by weight, add it to a high-speed mixer, and heat it at a temperature of 55°C , mixed for 35 minutes at a rotating speed of 2000r / min, after mixing, it will be active light...

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Abstract

The invention discloses a foamed micropore layer of artificial leather for lining of PE shoes and a method for preparing artificial leather by using the same. The components of the foamed micropore layer comprise polyethylene, ethylene-vinyl acetate copolymer, styrene-butadiene copolymer, active calcium carbonate, azodicarbonamide, zinc oxide, white pigment, dicumyl peroxide and antioxidant. The preparation method comprises the following steps of: adding the prepared raw materials to a high-speed mixer and mixing the raw materials; conveying the mixed material to a hopper of an extruder and plasticizing the material; conveying the plasticized material to a four-roller calendar and rolling the material into a thin film; laminating the thin film on a fabric foundation in a rolling manner and trimming the thin film; winding the thin film by a winding machine to form the semi-finished product, conveying the semi-finished product to an oven and carrying out the cross-linking foaming on the semi-finished product; taking the foamed product out of the oven, embossing the foamed product on an embossing roller, cooling the foamed product and pressing down the embossing roller to obtain the artificial leather for the lining of PE shoes. By adopting the technical scheme of the invention, the artificial leather for the lining of PE shoes has the advantages of high arc stiffness, good cold resistance, high foaming ratio, vulcanization resistance and the like, and has low labor intensity, low energy consumption and short treatment period.

Description

1. Technical field: [0001] The invention relates to an artificial leather, in particular to a PE-shoe lining artificial leather foamed microporous layer and a method for preparing artificial leather by using the foamed microporous layer. 2. Background technology: [0002] Artificial leather for shoe lining is generally polyvinyl chloride PVC foamed artificial leather. The artificial leather prepared by this method has disadvantages such as low stiffness and poor cold resistance; and the raw material formula of the foamed microporous layer contains a large amount of liquid plasticizer, stable In this way, in the production process, a large amount of plasticizers and stabilizers will evaporate, causing environmental pollution and not conducive to environmental protection. Ordinary foamed polyethylene PE artificial leather can only be used in student schoolbags, etc., because this kind of artificial leather has low foaming ratio and is not resistant to vulcanization, so it cann...

Claims

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Application Information

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IPC IPC(8): C08L23/06C08L23/08C08L31/04C08L53/02C08K13/06C08K9/06C08K3/26C08K3/22C08K5/14D06N3/04D06N3/10C08J9/10B29B7/28B29C47/92A43B23/07B29C48/92
CPCB29C48/92B29C2948/92647B29C2948/92704B29C2948/92895B29C2948/92923
Inventor 袁飞施绍献岳小金贾世奇田青亮王聚中曹刚
Owner 袁飞
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