Method for emulsifying molybdenum beneficiation collecting agent

A collector and emulsifier technology, which is applied in the emulsification field of molybdenum beneficiation collectors, can solve the problems of difficulty in further improving the beneficiation recovery rate, low water solubility and dispersibility, low diesel chemical activity, etc., to improve the collection effect. , the effect of enhancing dispersibility and reducing tailings grade

Active Publication Date: 2012-08-29
CHINA MOLYBDENUM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Since diesel has neither polar functional group nor polarity in structure, and the carbon and hydrogen atoms in the whole molecule are bound by covalent bonds and are in a saturated state, the chemical activity of diesel is very low, and ions cannot be ionized in aqueous solution. It is impossible to have chemical adsorption or surface chemical reaction when interacting with the mineral surface. It can only interact with the mineral surface through van der Waals force relying on physical adsorption. Because diesel oil is difficult to dissolve in water, its water solubility and dispersibility in the pulp are low, mainly It exists in the state of oil beads (molecular aggregates), and the oil film formed on the surface of the mineral is thicker, and the contact with the ore particles is not sufficient, which makes it difficult to further increase the recovery rate of ore dressing

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0011] The emulsification method of molybdenum ore dressing collector described in the present embodiment comprises the following steps:

[0012] (1) Put the emulsifier sodium alkylbenzene sulfonate into hot water above 65°C, stir for 10 minutes to fully dissolve it, and the mass ratio of sodium alkylbenzenesulfonate to water is 1:5;

[0013] (2) The emulsifier obtained in step (1) is mixed with diesel oil, sodium silicate, and water by mass percentage: 0.02% emulsifier, 6% diesel oil, 1% sodium silicate, and 92.98% water, and stir for 20 minutes to collect agent mixture;

[0014] (3) The collector mixed solution obtained in step (2) is injected into the ELR / 3 high-shear three-stage emulsification pump (the rotating speed is 2890rpm, and the flow rate is 12m 3 / h), shear, and recirculate 2 times to obtain an emulsified collector.

Embodiment 2

[0016] The emulsification method of molybdenum ore dressing collector described in the present embodiment comprises the following steps:

[0017] (1) with step (1) in example 1;

[0018] (2) The emulsifier obtained in step (1) is mixed with diesel oil, sodium silicate, and water by mass percentage: 0.04% emulsifier, 7% diesel oil, 1.2% sodium silicate, and 91.76% water, and stir for 20 minutes to collect agent mixture;

[0019] (3) Step (3) in Example 1.

Embodiment 3

[0021] The emulsification method of molybdenum ore dressing collector described in the present embodiment comprises the following steps:

[0022] (1) with step (1) in example 1;

[0023] (2) The emulsifier obtained in step (1) is mixed with diesel oil, sodium silicate, and water by mass percentage: 0.06% of emulsifier, 8% of diesel oil, 1.5% of sodium silicate, and 90.44% of water, and stirred for 20 minutes to collect agent mixture;

[0024] (3) Step (3) in Example 1.

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Abstract

The invention discloses a method for emulsifying a molybdenum beneficiation collecting agent, comprising the following steps of: (1) putting sodium alkyl benzene sulfonate of an emulsifier into hot water the temperature of which is higher than 65 DEG C, stirring for 10min so as to enable the emulsifier to be sufficiently dissolved, wherein the mass ratio of sodium alkyl benzene sulfonate to the water is 1:5; (2) mixing 0.02-0.1 mass percent of emulsifier obtained in the step 1 and 6-10 mass percent of diesel oil, 1-2 mass percent of sodium silicate and 92.98-87.9 percent of water, stirring for 20min, and then obtaining a mixed liquor of the collecting agent; and (3) injecting the mixed liquor of the collecting agent which is obtained in the step 2 to a high shear emulsification pump, shearing and then circulating 2 times, and finally obtaining the emulsified collecting agent. The invention improves the water solubility and the dispersity of the collecting agent and reduces the final tailings grade, and the total yield is 0.5 percent higher than that of a process singly using the collecting agent. Meanwhile, the unit consumption of the collecting agent is reduced by 20 percent, andthe unit consumption of a foaming agent is reduced by 9.5 percent.

Description

technical field [0001] The invention belongs to the technical field of molybdenum beneficiation, and mainly relates to an emulsification method of a molybdenum beneficiation collector. Background technique [0002] At present, the collector used in molybdenum beneficiation technology is basically diesel oil. Since diesel has neither polar functional group nor polarity in structure, and the carbon and hydrogen atoms in the whole molecule are bound by covalent bonds and are in a saturated state, the chemical activity of diesel is very low, and ions cannot be ionized in aqueous solution. It is impossible to have chemical adsorption or surface chemical reaction when interacting with the mineral surface. It can only interact with the mineral surface by means of physical adsorption through van der Waals force. Because diesel oil is difficult to dissolve in water, its water solubility and dispersibility in the pulp are low, mainly It exists in the state of oil beads (molecular agg...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B03D1/001B03D101/02
Inventor 谢凤祥陈忠典刘红亮车文芳姚良俊周旭东徐文松胥博升
Owner CHINA MOLYBDENUM
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