Crosslinkable materials based on organosilicon compounds
一种交联组合物、化合物的技术,应用在有机化学、周期表第4/14族元素的化合物、化学仪器和方法等方向,能够解决不足粘着剂等问题
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Embodiment 1
[0177] Example 1 (E1)
[0178] Preparation of Polymer 1
[0179] 970 gram average molecular weight is 18,000g / mol, OH number is 7.0mg KOH / g, molar mass distribution Mw / Mn is 1.1 and the poly(propylene glycol) glycol content of monoalcohol content that is 23,000mPa·s low (with " The trade name of Acclaim Polyol 18200N” was purchased from BayerMaterialScience AG, Germany), 30 g of 3-isocyanatopropyl-trimethoxysilane and 0.1 g of bismuth octoate were reacted at 90 ° C for 1 hour, and then 1 g of methanol was added to capture isocyanate groups . The reaction product was cooled to room temperature and stored in the absence of moisture.
[0180] A clear, colorless polymer with a viscosity of 35,000 mPa·s was obtained.
[0181] 400 g of polymer 1 thus prepared, 250 g of polypropylene glycol-monohydroxyl-monobutyl ether having a viscosity of 240 mPa·s at 50° C. and a water content of 120 ppm according to Karl-Fischer titration were dissolved in 1.6 6.4 grams of N-(2-ethoxyphenyl)-...
Embodiment 2
[0183] Example 2 (E2)
[0184] The procedure described in Example 1 was repeated except that the mixture was composed of about 25% methyl-1,2,2,6,6-pentamethyl-4-piperidinyl sebacate and about 75% 3 g of HALS mixture consisting of bis(1,2,2,6,6-pentamethyl-4-piperidinyl) sebacate, also using 3 g of CAS dissolved in 5 g of dipropylene glycol dimethyl ether Polymer HALS No. 192268-64-7 (with The product name of 2020 was purchased from Bodo, Germany Chemie).
[0185] After 1 day of storage at room temperature, tests 1 to 3 were carried out. The results are summarized in Table 1.
Embodiment 3
[0186] Example 3 (E3)
[0187] The procedure described in Example 1 was repeated, except that instead of 6.4 g of N-(2-ethoxyphenyl)-N'-(4-isododecylphenyl) dissolved in 1.6 g of xylene Ethylenediamine, using 6.0 g of N-(2-ethoxyphenyl)-N'-(2-ethylphenyl)ethylenediamide dissolved in 24 g of 1-methyl-2-pyrrolidone ( by The trade name of 312 was purchased from Bodo, Germany Chemie).
[0188] After 1 day of storage at room temperature, tests 1 to 3 were carried out. The results are summarized in Table 1.
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