Ink jet treatment liquid, ink jet recording method, and recorded matter
A processing liquid and inkjet technology, applied in the direction of copying/marking method, thin material processing, ink, etc., can solve the problems that the processing liquid cannot be obtained, the storage stability cannot be fully satisfied, and cannot be guaranteed.
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[0041] For example, cationic polyurethanes obtained by the following preparations (1) to (2) and the like are mentioned, and an aqueous dispersion which is a composition obtained by dispersing cationic polyurethanes in water is particularly preferable.
[0042] The preparation of cationic polyurethane is as follows: (1) use polyisocyanate (A) and polyester polyol (B1) as polyol for polyurethane reaction, and use chain extender (C) with tertiary amino group simultaneously to prepare polyurethane In the prepolymer, a part of the tertiary amino groups is neutralized with an acid or quaternized with a quaternizing agent so that the amine value is in the range of 1 to 40 (KOHmg / g), whereby a cationic polyurethane can be obtained in the form of a composition. In addition, (2) using the polyisocyanate (A), the polycarbonate polyol (B2), the chain extender (C) having the tertiary amino group, and the polyisocyanate containing 50% by mass or more of ethylene oxide chain The alkylene ox...
Embodiment 1
[0117] In Example 1, "HYDRAN CP-7010" (manufactured by Dainippon Ink Chemical Industry Co., Ltd.) was used as the cationic polyurethane, and "PAA-01" (manufactured by Nitto Industries, Ltd.) was used as the polyamine and / or polyamine derivatives. Co., Ltd.).
[0118] (Composition of treatment liquid 1)
[0119] HYDRAN CP-7010 (solid content 30%) 15 parts
[0120] PAA-01 (solid content 15%) 10 parts
[0121] Ethylene glycol-n-hexyl ether 0.5 part
[0122] 1,2-pentanediol 4 parts
[0123] BYK-347 0.3 parts
[0124] 10 parts of N-methyl-2-pyrrolidone
[0125] Triethanolamine 0.5 parts
[0126] water balance
[0127] The treatment solution having the above composition was thoroughly mixed and stirred, and filtered with a membrane filter having a pore size of 10 μm to prepare a treatment solution 1 .
Embodiment 2
[0129] In Example 2, "HYDRAN CP-7020" (manufactured by Dainippon Ink Chemical Industry Co., Ltd.) was used as the cationic polyurethane, and "PAS-A-1" (manufactured by Japan Ink Chemicals Co., Ltd.) was used as the polyamine and / or polyamine derivative. Tobobo Co., Ltd.).
[0130] (Composition of treatment solution 2)
[0131] HYDRAN CP-7020 (solid content 40%) 10 parts
[0132] PAS-A-1 (solid content 24%) 5 parts
[0133] Diethylene glycol-n-hexyl ether 2.5 parts
[0134] 1,2-hexanediol 3 parts
[0135] BYK-348 0.5 parts
[0136] 10 parts of N-methyl-2-pyrrolidone
[0137] Tripropanolamine 0.5 part
[0138] water balance
[0139] The treatment liquid having the above composition was thoroughly mixed and stirred, and filtered through a membrane filter with a pore diameter of 10 μm to prepare a treatment liquid 2 .
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