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Pulp and black liquor prepared by grass type raw material, preparation method and use thereof

A grass and raw material technology, applied in the field of pulp and black liquor prepared from grass raw materials, can solve the problems of high carbohydrate content, low pulp quality, difficult recycling, etc., to reduce degradation, ensure strength, shorten The effect of holding time

Active Publication Date: 2009-06-10
SHANDONG FUYIN PAPER & ENVIRONMENTAL PROTECTION TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

3. Due to the high content of silicon and carbohydrates in the raw materials, the viscosity of the black liquor is high and the recovery is difficult
4. Grass fibers contain a large number of miscellaneous cells, which pose a series of hazards to papermaking
[0008] Heilongjiang Papermaking published an article entitled "Optimized Cooking Conditions by Straw Ammonium Sulfite Method" in No. 4, 2003, which disclosed the optimal conditions for cooking by straw ammonium sulfite method, but the quality of the pulp prepared by this cooking method not tall
[0009] In addition, the application range of paper products made from unbleached pulp with low whiteness is wider and wider, such as corrugated paper, lunch boxes, packaging paper, etc., but the strength of unbleached pulp made from straw raw materials is not very high. Requires addition of other wood-derived pulps to increase strength, thus increasing cost

Method used

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  • Pulp and black liquor prepared by grass type raw material, preparation method and use thereof
  • Pulp and black liquor prepared by grass type raw material, preparation method and use thereof
  • Pulp and black liquor prepared by grass type raw material, preparation method and use thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0530] The rice straw of 30 mm after preparation is impregnated with an impregnating screw. The impregnating solution is an alkali solution with an alkali content of 4% of the absolute dry raw material in terms of sodium hydroxide, with a liquid ratio of 1:4 and 85 After insulated and mixed for 40 minutes at ℃, the impregnated raw materials were sent to steaming balls. Add cooking agent to the steaming ball, the amount of ammonium sulfite is 11% of the absolute dry raw material, and the liquid ratio is 1:3; put steam into the steaming ball for heating, heat it up to 125 ° C for 40 minutes, and carry out small Let off steam, continue to heat up to 170°C, and keep warm for 75 minutes.

[0531] After cooking, a pulp with a hardness of potassium permanganate value of 18, which is equivalent to a kappa value of 27, is obtained. The cooked pulp is then squeezed. The high-hardness pulp with a concentration of 15% obtained after cooking can enter from the inlet of the twin-roll pres...

Embodiment 2

[0534] Cook the rice straw with a length of 15-20mm after conventional dry preparation: add cooking agent to the steaming ball, the amount of ammonium sulfite is 9% of the absolute dry raw material, and the liquid ratio is 1:4; Put steam into the medium for heating, heat it up to 130°C and keep it warm for 20 minutes, perform a small release of steam, continue heating to 165°C, and keep it warm for 90 minutes. After cooking, a pulp with a hardness of potassium permanganate value of 24, which is equivalent to a kappa value of 39, is obtained. Then squeeze the high-hardness pulp after cooking, and enter the high-hardness pulp with a concentration of 10% after cooking from the entrance of the variable-diameter single-screw squeezer to squeeze out the black liquor. After the black liquor is squeezed out, the concentration is 25%. The pulp is discharged from the outlet of the pulping machine. The beating degree of the high-hardness pulp was 24°SR before pulping, and the beating de...

Embodiment 3

[0538] Put the rice straw with a length of 20-25mm after conventional preparation into the steaming ball for cooking, add cooking agent into the steaming ball, the amount of ammonium sulfite is 10% of the absolute dry raw material, and the liquid ratio is 1:2 , feed steam for heating, heat up to 120°C and keep warm for 30 minutes, perform a small release of steam for 25 minutes, continue to heat up to 173°C, and keep warm for 60 minutes. After cooking, obtain a high-hardness pulp with a potassium permanganate value of 25, which is equivalent to a kappa value of 43, and then squeeze the high-hardness pulp, that is, after cooking, the high-hardness pulp with a concentration of 8% is obtained from a variable diameter The inlet of the twin-screw squeezer enters, squeezes out the pulp, and after the black liquor is squeezed out, the pulp with a concentration of 20% is discharged from the outlet of the squeezer. The beating degree of the high-hardness pulp was 22°SR before pulping, ...

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Abstract

The invention relates to unbleached pulp prepared by the ammonium sulfite cooking of a rice straw raw material and a preparation method thereof. The whiteness of the unbleached pulp is 35 to 48 percent ISO, the fracture length is between 5.0 and 7.5km, the tearability is between 200 and 275mN, and the folding times are between 30 and 100. The method comprises the steps of ammonium sulfite cookingand oxygen delignification, wherein the ammonium sulfite cooking is to cook the raw material into the pulp the harness of which has a potassium permanganate value of between 16 and 28 and is equivalent to a Kappa number of between 24 and 50. The unbleached pulp has higher strength, particularly has the fracture length and the folding times which exceed the level of hardwood pulp, can be used for manufacturing corrugated paper, lunch boxes, and packing paper which have quite high strength, or is applied to manufacturing other paper products more widely only by adding little wood pulp, greatly reduces the cost for products, and also ensures the strength of the products. The method can ensure that lignin is effectively removed and also try to reduce the degradation of fiber, thereby obtaining the unbleached pulp with good strength.

Description

technical field [0001] The invention relates to pulp and black liquor, in particular to pulp and black liquor prepared from grass raw materials, a preparation method and application thereof. Background technique [0002] At present, most of the world's pulp raw materials are wood, especially in developed countries such as the United States, Canada, Nordic countries and Russia, almost all of which are made of wood. As the demand for lumber increases year by year, the price of lumber also continues to rise. Many countries with low timber resources need to import large quantities of timber, and even countries with abundant timber resources, such as Canada, are expected to have a shortage of logs before long. Therefore, the problem of raw materials has become a major issue in the development of pulping industry in various countries, and the source of pulping raw materials is also expanding. [0003] In the pulp and paper industry, the use of grass raw materials for pulping is ...

Claims

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Application Information

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IPC IPC(8): D21H11/12D21C3/00D21C7/00D21C3/14D21C3/02D21C9/00D21C11/00
Inventor 李洪法宋建军宋明信陈松涛杨吉慧毕衍金王万磊赵淑晶郭良进
Owner SHANDONG FUYIN PAPER & ENVIRONMENTAL PROTECTION TECH
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