Curing fluorine containing paint in normal temperature with quadric-polymerization
A room temperature curing and quaternary copolymerization technology, applied in the direction of coating, etc., can solve the problems of easy crystallization and poor stability, and achieve the effects of low surface tension, strong adhesion, stain resistance and high chemical inertness
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Embodiment 1
[0017] A normal temperature curing fluorine-containing coating prepared by a four-component copolymerization method, its composition includes: tetrafluoroethylene, fatty acid vinyl ester, aliphatic enol and aliphatic alkene acid, the solid content is 70%, the hydroxyl value is 75mgkoH / g, the acid The value is 15mgkoH / g, the viscosity is 54s in 4 cups, and the specific gravity is 1.25. The weight ratio of tetrafluoroethylene, fatty acid vinyl ester, aliphatic enol and aliphatic alkenoic acid in the polymer is: 45:40 :18:3, and its chain structure is: R 1 =C 1 ~C 3 n-alkyl; R 2 =(CH) n , n=6; R 3 =(CH 2 ) n , n=10.
Embodiment 2
[0019] A fluorine-containing coating cured at room temperature prepared by a four-component copolymerization method. Its composition includes: tetrafluoroethylene, fatty acid vinyl ester, aliphatic enol and aliphatic alkenoic acid, the solid content is 65%, the hydroxyl value is 65mgkoH / g, and the acid The value is 10mgkoH / g, the viscosity is 50s in 4 cups, and the specific gravity is 1.20. The weight ratio of tetrafluoroethylene, fatty acid vinyl ester, aliphatic enol and aliphatic alkenoic acid in the polymer is: 40:30 :14:3, its chain schematic structure is: R 1 =C 1 ~C 3 n-alkyl; R 2 =(CH) n , n=5; R 3 =(CH 2 ) n , n=7.
Embodiment 3
[0021] A fluorine-containing coating cured at room temperature prepared by a four-component copolymerization method. Its composition includes: tetrafluoroethylene, fatty acid vinyl ester, aliphatic enol and aliphatic alkenoic acid, the solid content is 60%, the hydroxyl value is 40mgkoH / g, and the acid The value is 8mgkoH / g, the viscosity is 45s in 4 cups, and the specific gravity is 1.10. The weight ratio of tetrafluoroethylene, fatty acid vinyl ester, aliphatic enol and aliphatic alkenoic acid in the polymer is: 35:25 :12:2, and its chain schematic structure is: R 1 =C 1 ~C 3 n-alkyl; R 2 =(CH) n , n=1; R 3 =(CH 2 ) n , n=1.
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