Method for preparing smooth cord-grass active carbon for treating cadmium-containing waste water
A technology of Spartina alterniflora and activated carbon, which is applied in chemical instruments and methods, adsorption water/sewage treatment, and other chemical processes, can solve problems such as suffocation and death of marine organisms, affect tidal flat aquaculture, and decline in water quality, and achieve a good society Benefits, good environmental effects
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Embodiment 1
[0023] (1) Dry Spartina alterniflora in the shade, take the stems, dry them in an oven at 120°C, pulverize them with a pulverizer, and pass through a 100-mesh sieve.
[0024] (2) Spartina alterniflora powder was leached with 1% (mass ratio) sulfuric acid solution, wherein the mass ratio of sulfuric acid solution to Spartina alterniflora was 1:10, and the reaction time was 4 hours.
[0025] (3) The solid-liquid mixture is filtered, and the filter residue is injected into a phosphoric acid solution, wherein the mass ratio of phosphoric acid to the original dried Spartina is 1:1, and the reaction time is 12 hours.
[0026] (4) After drying the mixture of Spartina phosphate at 120°C, put it into a tubular resistance furnace, 2 The activation is carried out under the following conditions, wherein the calcination temperature is 700°C, the temperature rise is 5°C / min, and the calcination time at 700°C is 2h.
[0027] (5) Utilize clear water to wash the activated carbon obtained by c...
Embodiment 2
[0030] With other conditions unchanged, the temperature in (4) of Example 1 was changed to 600° C., and the final yield was 45%.
[0031] The activated carbon product obtained by this embodiment has an adsorption capacity of 41.37mgCd for cadmium 2+ / mg activated carbon, the adsorption efficiency of 20mg / L cadmium-containing solution is above 98.9%, and the concentration of 10mg / L cadmium-containing solution after treatment is 0.07mg / L, which has reached the national first-level emission standard.
Embodiment 3
[0033] Other conditions remained unchanged, the reaction time in (3) of Example 1 was changed to 20h, the temperature in (4) of Example 1 was changed to 500°C, and the final yield was 47%.
[0034] The activated carbon product obtained by this embodiment is 28.1mgCd for the adsorption capacity of cadmium 2+ / mg activated carbon, the adsorption efficiency of 20mg / L cadmium-containing solution is above 96.1%, and the concentration of 10mg / L cadmium-containing solution after treatment is 0.07mg / L, reaching the national first-level emission standard.
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