Polyethylene multilayer microporous membrane, battery separator using same, and battery
一种微多孔膜、聚乙烯的技术,应用在电池、二次电池、电池组零部件等方向,能够解决变形小等问题
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Embodiment 1
[0157] (1) Production of the first microporous membrane
[0158] The mass average molecular weight (Mw) is 2.0×10 6 20% by mass of ultra-high molecular weight polyethylene (UHMWPE) and Mw of 3.5×10 5 In 100 parts by mass of a polyethylene composition composed of 75% by mass of high-density polyethylene (HDPE), as an antioxidant, dry-mixed tetra[methylene-3-(3,5-di-tertbutyl-4- Hydroxyphenyl)-propionate] methane 0.2 parts by mass. Among them, the melting point measured for the polyethylene composition composed of UHMWPE and HDPE was 135°C, and the crystal dispersion temperature was 90°C.
[0159] The Mw of UHMWPE and HDPE is determined by gel permeation chromatography (GPC) under the following conditions.
[0160] · Measuring device: GPC-150C manufactured by Waters Corporation
[0161] ·Column: Shodex UT806M manufactured by Showa Denko Corporation
[0162] ·Column temperature: 135℃
[0163] ·Solvent (mobile phase): o-dichlorobenzene
[0164] ·Solvent flow rate: 1.0ml / min
[0165] ·...
Embodiment 2
[0177] A polyethylene double-layer microporous membrane was produced in the same manner as in Example 1, except that the mixing ratio of the resin mixture for the second porous layer was 25% by mass of UHMWPE, 55% by mass of HDPE, and 20% by mass of PBT.
Embodiment 3
[0179] The first and second microporous membranes were produced so that the thickness of each was 50μm, and the first microporous membrane was laminated on both sides of the obtained second microporous membrane and joined, except that it was the same as in Example 1 To make a polyethylene three-layer microporous membrane.
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