Liquid developer and image forming apparatus
A developer and liquid technology, applied in the direction of developer, electric recording process using charge pattern, equipment for electric recording process using charge pattern, etc., can solve the problem of toner uniformity, particle agglomeration, and difficulty in forming resolution Eliminates problems such as toner images, and achieves excellent dispersion stability and excellent fixing characteristics
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[0121] [Preparation of associated particles]
[0122] First, an example of a method for producing associated particles in which resin fine particles mainly composed of polyester resin are associated will be described.
[0123] Any method can be used to prepare the associated particles, but in this embodiment, a dispersoid (fine particles) mainly composed of a polyester resin (toner constituent material) is dispersed in an aqueous dispersant composed of an aqueous liquid to obtain a The resulting water-based emulsion is obtained, and the dispersoids in the water-based emulsion are associated to obtain associated particles.
[0124] (water emulsion)
[0125] First, the aqueous emulsion used in this embodiment will be described.
[0126] The aqueous emulsion obtained through the aqueous emulsion preparation process described later has a configuration in which dispersoids (fine particles) are finely dispersed in an aqueous dispersant composed of an aqueous liquid.
[0127] -Aqu...
Embodiment 1
[0312]
[0313] The fatty acid monoester-containing liquid constituting the insulating liquid was prepared as follows.
[0314] First, crude soybean oil was refined as follows to obtain refined soybean oil.
[0315] First, crude soybean oil is roughly refined by a low-temperature crystallization method using methanol, diethyl ether, petroleum ether, acetone, etc. as a solvent.
[0316] Next, 300 parts by volume of crudely refined crude soybean oil (first crudely refined oil) was put into the flask, and then 100 parts by volume of boiling water was poured into the flask to close the flask.
[0317] Next, the flask was shaken to mix the crude soybean oil (first crude refined oil) and boiling water.
[0318] Next, the flask was left still until the liquid mixture in the flask separated into three layers.
[0319] After complete separation was confirmed, the flask was moved to cold storage for 24 hours.
[0320] Then, transfer the unfrozen ingredients to other flasks.
[032...
Embodiment 2
[0355] Instead of the soybean oil fatty acid, except having used the rapeseed oil fatty acid prepared as follows, it carried out similarly to the said Example 1, and manufactured the liquid developer corresponding to each color.
[0356] The crude rapeseed oil was refined by the same operation as the soybean oil of Example 1 to obtain refined rapeseed oil (hereinafter, simply referred to as rapeseed oil.). The rapeseed oil mainly contains fatty acid glycerides with oleic acid as the main component, and the unsaturated fatty acid glycerides in the rapeseed oil is 98wt%. In addition, the oleic acid component and the linoleic acid component accounted for 52 mol% and 24 mol%, respectively, of the total fatty acid components.
[0357] Next, a transesterification reaction of the rapeseed oil and methanol was performed, and glycerin produced by the reaction was removed to obtain a liquid mainly composed of fatty acid monoesters. By further refining this liquid, rapeseed oil fatty ac...
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