Gas-sensitive conducting composite material of aqueous polyurethane group and preparation method
A conductive composite material and water-based polyurethane technology are applied in the field of water-based polyurethane-based gas-sensing conductive composite materials and their preparation to achieve excellent electrical conductivity and reduce the effect of percolation value.
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[0023] The ratio table 1 of embodiment 1~8, its preparation method concrete steps are as follows:
[0024] 1. Synthesis of permanent polyurethane prepolymer: Add the dried oligomer polyol and diisocyanate into the reaction kettle according to the ratio of 6:1 to 2:1, add the catalyst, and react at 70-120°C 8-14 hours, the amount of catalyst used is 0.5% of the amount of polyol.
[0025] 2. Add pre-dried conductive carbon black to the reaction kettle and continue to react for 8-14 hours.
[0026] 3. Cool down to below 50°C, add neutralizing agent triethylamine to neutralize for 1 hour
[0027] 4. Add deionized water for emulsification, and at the same time add chain extender ethylenediamine for chain extension reaction for 3 to 6 hours.
[0028] 5. Emulsion discharge is filtered to obtain composite material emulsion, which is stored for later use.
[0029] 6. The emulsion is coated on the electrode plate and dried at room temperature for 2 weeks to obtain a composite materia...
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