The present invention relates to a heterocyclic organic photoelectric material and its preparation method and application. The material is a compound shown in the following formula I: the material of the present invention is a heterocyclic aromatic hydrocarbon derivative with excellent chemical stability, electron mobility, etc., and is synthesized in one step , high conversion rate, the material has the advantages of excellent electron transport characteristics and hole mobility, good thermal stability, high efficiency, low driving voltage and not easy to crystallize, it is used in electroluminescent devices with low driving voltage and high brightness, Good thermal stability, long half-life period, low cost, and 2-3 times longer lifespan.