Polarizer, method of manufacturing the same, polarizing plate, optical film, and image display

Abstract

A polarizer of the invention comprises a polyvinyl alcohol-based film which is at least dyed with at least iodine and uniaxially stretched, having a single transmittance of 43% or more, a polarizing efficiency of 99.9% or more, and a dichroic ratio of 30 or more, wherein the dichroic ratio is calculated from a parallel transmittance (Tp) and a crossed transmittance (Tc) at a wavelength of 440 nm, and have good hue.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS[0001]This application is a divisional application of U.S. Ser. No. 10 / 553,958, filed Oct. 19, 2005, which is a National Phase filing of PCT / JP2004 / 005548, filed on Apr. 19, 2004, which is based on and claims the benefit of priority from Japanese Patent Application No. 2003-115650, filed Apr. 21, 2003, the entire contents of which being incorporated herein by reference.TECHNICAL FIELD[0002]The invention relates to a polarizer and a method of manufacturing the same. The invention also relates to a polarizing plate using the polarizer and to an optical film using the polarizing plate or the like. The invention further relates to an image display such as a liquid crystal display, an organic electro-luminescent (EL) display and a Plasma Display Panel (PDP) using the polarizing plate, the optical film, or the like.BACKGROUND ART[0003]Conventionally, image displays such as liquid crystal displays use polarizing plates comprising a laminate of a polar...

AI Technical Summary

Benefits of technology

[0007]It is an object of the invention to provide a polarizer having good hue. It is another object of the invention to provide a polarizer having good hue and good durability.

[0008]It is also another object of the invention to provide a method of manufacturing a polarizer having good hue. It is still another object of the invention to provide a method of manufacturing a polarizer having good hue and good durability.

[0021]In this point of view, the content of iodine in the polarizer is preferably from 1.5 to 2.5% by weight, more preferably from 1.7 to 2.4% by weight, still more preferably from 2 to 2.3% by weight. If the iodine content is too high, the polarizing plate has insufficient durability and is easily discolored red at high temperatures. If the iodine content is too low, the polarizing efficiency is easily lowered. The content of potassium in the polarizer is preferably from 0.2 to 0.6% by weight, more preferably from 0.3 to 0.58% by weight, still more preferably from 0.4 to 0.57% by weight. If the potassium content is too high, the polarizing plate has insufficient durability and is easily discolored red at high temperatures. If the potassium content is too low, the polarizing efficiency is easily lowered.

[0033]In the method of manufacturing the polarizer, the iodine dyeing step may be performed together with the stretching step. While the stretching may be performed in a pre-step before the step in the aqueous boric acid solution (the stretching bath), the stretching in the pre-step is preferably performed together with the iodine dyeing step in terms of preventing wrinkling of the film swelling in water.

Problems solved by technology

Thus, there has been a problem that conventional liquid crystal displays using such polarizing plates can become slightly yellow when white viewing and can become blue when black viewing.

According to the method as disclosed in the publication, however, the resulting hue is not sufficiently good in each of the parallel and crossed Nicol configurations.

There has also been a problem that iodine-type polarizers do not have sufficient durability and two pieces of such polarizers in the crossed Nicol configuration can cause polarization dropout at long wavelengths and can be discolored red when placed in a heated environment.

According to these patent literatures, however, it is needed to make polarizers contain zinc ions, and thus there are problems about the zinc precipitate on the surface of polarizers, the complicated control of concentration, and skin irritation.