Process to sequester CO2 in natural gas hydrate fields and simultaneously recover methane
a natural gas hydrate and co2 technology, applied in the field of process for storage and sequestration of carbon dioxide (co2), can solve the problems of environmental damage to the host and method has not yet been successfully demonstrated
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[0020] The invention claimed herein is a method for sequestration and storage of CO2 in which the CO2 to be sequestered and stored is injected into a subterranean methane hydrate field whereby the methane in the methane hydrate field is displaced by the CO2 and, in so doing, the methane is released for collection.
[0021] Both CO2 and methane form structure I hydrates. At temperatures below about 283° K, there is a pressure range in which methane hydrate is unstable and CO2 hydrate is stable. The heat released from the formation of CO2 gas hydrate is larger than that needed for methane hydrate dissociation:
CH4(H2O)n→CH4+nH2O Δhf=54.49 KJ / mole
CO2(H2O)n→CO2+nH2O Δhf=57.98 KJ / mole
where n is the hydration number for methane hydrate and CO2 hydrate (assuming that n is 6.15 for both methane and CO2). It should be noted that n is dependent on pressure, temperature and the composition of the gas in the gas phase. This suggests that under certain pressure-temperature conditions, the repla...
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