Spectral catalysts

a spectral catalyst and catalyst technology, applied in the field of spectral catalysts, can solve the problems of unfavorable reaction rate, and insufficient quantity of preferred products, and none of the methods are energy efficient,

Inactive Publication Date: 2002-03-14
GR INTELLECTUAL RESERVE LLC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0053] A wide variety of reactions can be advantageously affected and directed with the assistance of a spectral catalyst having a specific electromagnetic spectral pattern which transfers a predetermined quanta of energy to initiate, control and / or promote a reaction system. The spectral catalyst utilized in this invention can replace and provide the additional energy normally supplied by a physical catalyst. The spectral catalyst can act as both a positive catalyst to increase the rate of a reaction or as a negative catalyst to decrease the rate of reaction. Furthermore, the spectral catalyst can augment a physical chemical catalyst by utilizing both in a reaction system. The spectral catalyst can improve the activity of a chemical catalyst and may eliminate the high pressure and temperature requirements of many reactions. Also, the spectral catalyst can merely replace a specific quantity of the chemical catalyst, thereby reducing the high cost of physical catalysts in many industrial reactions.
[0054] In the present invention, the spectral catalyst provides electromagnetic radiation comprising a specific frequency or frequencies in a sufficient amount for a sufficient duration to initiate and / or promote a chemical reaction. With the absorption of electromagnetic energy from a spectral catalyst, a chemical reaction may proceed through one or several pathways including: energy transfer which can excite electrons to higher energy states for initiation of chemical reaction; ionize or dissociate reactants which may participate in a chemical reaction; stabilize end products; and energize or stabilize intermediates that participate in a chemical reaction.
[0074] An electromagnetic radiation emitting source should have the following characteristics: high intensity of the desired wavelengths, long life, stability and the ability to emit the electromagnetic energy in a pulsed and / or continuous mode.
[0083] The spectral patterns of both the reactant and product can be determined. This can be accomplished by the spectroscopic means mentioned earlier. Once the spectral patterns are determined with the specific frequency or frequencies of the interaction of the substance with electromagnetic radiation, the spectral patterns of the spectral catalyst can be determined. Using the spectral patterns of the reactants and products, a waveform analysis calculation can determine the energy difference between the reactants and products and the calculated spectral pattern is applied to the system to catalyze the reaction. The specific frequency or frequencies of the spectral pattern will provide the necessary energy input into the system to affect and initiate a chemical reaction.

Problems solved by technology

None of these methods are energy efficient and can produce either unwanted by-products, decomposition of the necessary transition state, or insufficient quantities of preferred products.
Additionally, with few exceptions, reaction rates increase with increasing temperature because of increased collisions.
But, with increased temperatures there are a number of problems which are introduced into the reaction system.
Also, there are a number of decomposition products which often produce fragments that are extremely reactive, but they are so short lived because of their thermodynamic instability that a preferred reaction may be dampened.
However, there are several drawbacks of using the known techniques of photochemistry, that being, utilizing a broad band of frequencies thereby causing unwanted side reactions, undue experimentation, and poor quantum yield.
Also, it has been observed that some substances, which if added in trace amounts, can slow down the rate of a reaction.
The exact mechanisms of catalytic actions are unknown but they can speed up a reaction that otherwise would take place too slowly to be practical.
There are a number of problems involved with known industrial catalysts: firstly, catalysts can not only lose their efficiency but also their selectivity, which can occur due to overheating or contamination of the catalyst; secondly, many catalysts include costly metals such as platinum or silver and have only a limited life span, some are difficult to rejuvenate, and the precious metals not easily reclaimed.
As a result, the spectra of molecules are much more complicated than those of atoms.
If a biological reaction can be catalyzed by only one enzyme then the loss of activity or reduced activity of that enzyme could greatly inhibit the specific reaction and could be detrimental to a living organism.

Method used

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Examples

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Effect test

example 2

H.sub.2O.sub.2>>>>>>platinum catalyst>>>>H.s-ub.2O+O.sub.2

[0092] The decomposition of hydrogen peroxide is an extremely slow reaction in the absence of catalysts. Accordingly, an experiment was performed to show that the physical catalyst, finely divided platinum, could be replaced with the spectral catalyst having the spectral pattern of platinum. Hydrogen peroxide was placed in 2 nippled quartz tubes. Both quartz tubes were inverted in beaker reservoirs filled with hydrogen peroxide and were shielded with card board wrapped in aluminum foil to block incident light. One of the wrapped tubes was used as a control. The other quartz tube set-up was exposed to a Fisher Scientific Hollow Cathode Lamp for platinum (Pt) using a Cathodeon Hollow Cathode Lamp Supply C610, at 80% maximum current (12 mAmps) for 24-96 hours. This tube set-up was monitored for increases in temperature to assure that any reaction was not due to thermal effects. A large bubble of O.sub.2 formed in the nipple of t...

example 3

[0094] It is well known that certain susceptible organisms have a toxic reaction to silver (such as E.coli, Strep pneumoniae, or Staph. aureus). In this regard, an experiment was conducted to show that the spectral catalyst emitting the spectrum of silver demonstrated a similar effect on these organisms. Wild E.coli, wild Strep pneumoniae, wild Staph. aureus and wild Salmonella typhi bacteria were plated onto standard growth medium in separate petri dishes. Each dish was placed at the bottom of an exposure chamber. A foil covered cardboard sheet with a patterned slit was placed over each culture plate. A Fisher Scientific Hollow Cathode Lamp for Silver (Ag) was inserted through the lid of the exposure chamber so that the spectral emission pattern of silver was irradiating the bacteria on the culture plate. A Cathodeon Hollow Cathode Lamp Supply C610 was used to power the Ag lamp at 80% maximum current (3.6 mAmps.) The culture plate was exposed to the Ag emission for 12-24 hours, and...

example 4

[0095] To further demonstrate that certain susceptible organisms which have a toxic reaction to silver would have a similar reaction to the spectral catalyst emitting the spectrum of silver. Cultures were obtained from the American Type Culture Collection (ATCC) which included Escherichia coli #25922, Klebsiella pneumonia, subsp Pneumoniae, #13883. The organisms were plated onto a standard growth medium in a petri dish. The dish was placed in the bottom of an exposure chamber such as the bottom of a coffee can. A Fisher Scientific Hollow Cathode Lamp for Silver (Ag) was inserted through the lid (aluminum foil covered coffee lid) of the exposure chamber so that the spectral emission pattern of silver was shining on the culture plate. A Cathodeon Hollow Cathode Lamp Supply C610 was used to power the Ag lamp at 80% maximum current (3.6 mAmps.) The culture plate was exposed to the Ag emission for 12-24 hours, and then incubated using standard techniques. Plates were examined using binoc...

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Abstract

A wide variety of reactions can be advantageously affected and directed by a spectral catalyst which duplicates the electromagnetic energy spectral pattern of a physical catalyst and when applied to a reaction system transfers a quanta of energy in the form of electromagnetic energy to control and / or promote the reaction system. The spectral catalysts utilized in this invention can replace and / or augment the energy normally provided to the reaction system by a physical catalyst. A spectral catalyst may also act as both a positive catalyst to increase the rate of a reaction or as a negative catalyst to decrease the rate of reaction.

Description

[0001] This is a divisional of co-pending application Ser. No. 09 / 098,883 filed Jun. 17, 1998 which claims the benefit of U.S. Provisional Application Ser. No. 60 / 049,910 filed Jun. 18, 1997.[0002] This invention relates to a novel method to control and / or direct a chemical reaction by exposing the reaction system to a frequency or frequencies of electromagnetic energy duplicating the spectral pattern of a physical catalyst.BACKGROUND OF INVENTION[0003] A chemical reaction can be activated or promoted either by the addition of energy to the reaction medium in the form of thermal and electromagnetic energy or by means of transferring energy through a physical catalyst. None of these methods are energy efficient and can produce either unwanted by-products, decomposition of the necessary transition state, or insufficient quantities of preferred products.[0004] It is generally true that chemical reactions occur as a result of collisions between reacting molecules. In terms of the collis...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): B01J19/12B01J37/34C01B5/00
CPCB01J19/121B01J19/122B01J19/127B01J37/342C07C1/00
Inventor BROOKS, JULIANA H.J.BLUM, BENTLEY J.
Owner GR INTELLECTUAL RESERVE LLC
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