Photosensitive resin composition, protective film and separator of LCD panel, forming method thereof and lcd panel
A technology of liquid crystal display panel and resin composition, which is applied in the direction of liquid crystal materials, chemical instruments and methods, and photoplate making process of patterned surface, etc., which can solve the problems of insufficient transparency and achieve the effect of suppressing pollution
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[0235] Hereinafter, although an Example and a comparative example are illustrated and this invention is demonstrated more concretely, this invention is not limited to these Examples.
Synthetic example 1
[0237] In the flask equipped with cooling tube and stirrer, drop 7 parts by weight of 2,2'-azobis(2,4-dimethylvaleronitrile), 200 parts by weight of propylene glycol monomethyl ether acetate. Then drop into 5 parts by weight styrene, 20 parts by weight methacrylic acid, 25 parts by weight methacrylic acid tricyclic [5.2.1.0 2,6 ]decane-8-yl ester, 25 parts by weight of 3-(methacryloyloxymethyl)-3-ethyl oxetane, 20 parts by weight of tetrahydrofurfuryl methacrylate, 5 parts by weight After replacing 1,3-butadiene with nitrogen, start stirring slowly. The temperature of the solution was raised to 70°C, and the temperature was maintained for 5 hours to obtain a polymer solution containing the copolymer [A-1]. The solid content concentration of the obtained polymer solution was 30.0% by weight, and the weight-average molecular weight of the polymer was 18,000 (the weight-average molecular weight was polyphenylene as measured by GPC (Gel Permeation Chromatography) HLC-8020 (manufa...
Synthetic example 2
[0239] In a flask equipped with a cooling tube and a stirrer, 7 parts by weight of 2,2'-azobis(2,4-dimethylvaleronitrile) and 200 parts by weight of diethylene glycol ethyl methyl ether were added. Then drop into 5 parts by weight styrene, 20 parts by weight methacrylic acid, 25 parts by weight methacrylic acid tricyclic [5.2.1.0 2,6 ] Decane-8-yl ester, 25 parts by weight of glycidyl methacrylate, 20 parts by weight of tetrahydrofurfuryl methacrylate, 5 parts by weight of 1,3-butadiene, after replacing with nitrogen, start to slowly Stir. The temperature of the solution was raised to 70°C, and the temperature was maintained for 5 hours to obtain a polymer solution containing the copolymer [A-2]. The solid content concentration of the obtained polymer solution was 31.0% by weight, and the weight-average molecular weight of the polymer was 20,000 (the weight-average molecular weight was polyphenylene as measured by GPC (Gel Permeation Chromatography) HLC-8020 (manufactured by ...
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