Environment-friendly type nanometer ceramic knife and manufacture method thereof
A nano-ceramic, environmentally friendly technology, applied in the field of ceramic materials, can solve the problems of high brittleness, dullness, low fracture toughness and bending strength, etc.
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Embodiment 1
[0012] 3Y-TZP powder (average particle size is 50nm) and 12Ce-TZP powder (average particle size is 60nm) provided on the market are used in the ratio of 3Y-TZP 85wt%, 12Ce-TZP 15wt%, respectively weighed 4.25 kg 3Y -TZP powder and 0.75 kg 12Ce-TZP powder, placed in lined with Al 2 o 3 In the ball mill tank of tiles, add polyvinyl alcohol aqueous solution (0.5% polyvinyl alcohol content) and zirconia grinding balls simultaneously; The weight ratio of powder: polyvinyl alcohol aqueous solution: grinding balls is 1:0.7:2, and then Ball milling and mixing for 10 hours, the mixed slurry was dried and pulverized, and passed through a 100-mesh sieve to obtain 3Y-TZP / 12Ce-TZP granulated powder. Then weigh a certain weight of the powder and pour it into a metal mold for dry pressing molding at a molding pressure of 100 MPa, hold the pressure for 3 seconds, and then slowly demould to obtain a ceramic knife green body with a certain strength and shape. The ceramic knife green body was ...
Embodiment 2
[0014] Using the same 3Y-TZP powder and 12Ce-TZP powder as above, weigh 5kg of the powder according to the ratio of 3Y-TZP 95wt% and 12Ce-TZP 5wt%. The above powder is placed in the liner with Al 2 o 3 In the ball mill cylinder of tiles, add deionized water and ZrO at the same time 2 Grinding balls. Powder: deionized water: grinding ball = 1:0.8:2.2. In addition, add liquid methyl cellulose as a dispersant, the amount added is 0.5% of the powder weight, and ball mill one piece for 15 hours to obtain a ceramic slurry with good fluidity, then perform vacuum defoaming to remove the bubbles. Then the slurry is injected into the gypsum mold, and after 8 hours, a wet blank of a ceramic knife with a certain strength and shape is formed in the gypsum mold cavity, and then demolded, then put into an oven and slowly heated to 50 ° C, constant temperature for 10 hours, and then heated to 110°C, constant temperature for 1 hour. After drying, the ceramic knife blank is placed in a hi...
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