Sulfurized hydrogenation catalyst, prepn. method
A hydrogenation catalyst and catalyst technology, applied in the direction of catalyst activation/preparation, physical/chemical process catalysts, chemical instruments and methods, etc., can solve problems such as uncombined
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Embodiment 1
[0019] Hydrogenation catalyst A: With γ-alumina as the carrier, the active metal composition is as follows: Mo content is expressed as MoO 3 The weight percentage is 23.7%, the Co content is 4.5% by weight in CoO, and the P content is in P 2 o 5 The weight percentage is 3.1%. (excluding the composition of vulcanizing agent)
[0020] Contain the preparation process of the above-mentioned composition catalyst of vulcanizing agent:
[0021] Take 1000 grams of gamma-alumina carrier, the specific surface area of the carrier is 296m 2 / g, pore volume 0.87ml / g, use 129 grams of molybdenum trioxide, 56 grams of cobalt carbonate, 30.6 grams of 85% phosphoric acid and appropriate amount of water to prepare 900ml aqueous solution, impregnate the above carrier, and dry the impregnated sample at 340°C for 4 hours , to prepare the catalyst intermediate, the Mo content is expressed as MoO 3 The weight percentage is 10%, the Co content is 2% by weight of CoO, and the P content is P 2 ...
Embodiment 2
[0023] Hydrogenation catalyst A: With γ-alumina as the carrier, the active metal composition is as follows: Mo content is expressed as MoO 3 The weight percentage is 25.8%, the Co content is 4.9% by weight in CoO, and the P content is in P 2 o 5 The weight percentage is 3.5%. (excluding the composition of vulcanizing agent)
[0024] Contain the preparation process of the above-mentioned composition catalyst of vulcanizing agent:
[0025] Take 1000 grams of gamma-alumina carrier, the specific surface area of the carrier is 296m 2 / g, pore volume 0.87ml / g, use 129 grams of molybdenum trioxide, 56 grams of cobalt carbonate, 30.6 grams of 85% phosphoric acid and appropriate amount of water to prepare 1300ml aqueous solution, impregnate the above carrier, and dry the impregnated sample at 340°C for 4 hours , to prepare the catalyst intermediate, the Mo content is expressed as MoO 3 The weight percentage is 8.9%, the Co content is 1.7% by weight in CoO, and the P content is P...
Embodiment 3
[0027] According to the method of embodiment 1, reduce the active metal content in the catalyst intermediate to be 15% (weight) of final catalyst active metal content, elemental sulfur consumption is 80% of theoretical requirement, other press embodiment 1 method, obtain catalyst C .
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