Nanometer antibacterial sterilizing plastic mother material and preparing method thereof

A plastic masterbatch and nanotechnology, applied in the field of preparation of nanometer antibacterial and antivirus plastic masterbatch, can solve the problems of unsatisfactory dispersion uniformity, affecting product performance and grade, uneven dispersion, etc. The effect of improving, obvious disintegration effect

Inactive Publication Date: 2004-12-08
HAIER GRP CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among the above processing techniques, the first technique is widely used because of its simple operation, but there are problems such as nano-powder agglomeration and uneven dispersion in plastic products; the second technique improves nano-TiO 2 The dispersion of the powder in the product, but because the melting performance of the masterbatch is poor during molding processing, and the melt viscosity after melting is high, the melting speed of the masterbatch is slow and the dispersion in the plastic melt is uneven , resulting in nano-TiO 2 The dispersion uniformity of particles in plastic products is not ideal
During the processing of the above process, due to the uneven dispersion of nano-powder and particle agglomeration, the color difference between different areas on the surface of plastic products and between batches is relatively large. In severe cases, appearance defects such as pitting can be found on the surface, which affects the performance of the product. And grade, at the same time the antibacterial effect and the effect of decomposing endotoxin also decline in varying degrees

Method used

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Examples

Experimental program
Comparison scheme
Effect test

specific Embodiment approach 1

[0032] A kind of nanometer antibacterial and antivirus plastic masterbatch, comprises the component of following ratio:

[0033] Nano-TiO surface modified by 2g rare earth aluminate coupling agent 2 Powder 250g;

[0034] Plastic resin: 1000g;

[0035] EVA resin: 100g;

[0036] White mineral oil: 2g;

[0037] Titanium dioxide: 65g;

[0038] Zinc stearate: 10g.

specific Embodiment approach 2

[0039] A kind of nanometer antibacterial and antivirus plastic masterbatch, comprises the component of following ratio:

[0040] Nano-TiO surface modified by 5g rare earth aluminate coupling agent 2 Powder 500g;

[0041] Plastic resin: 1100g;

[0042] EVA resin: 120g;

[0043] White mineral oil: 9g;

[0044] Titanium dioxide: 85g;

[0045] Zinc stearate: 7g;

[0046] Ultramarine 2g, network red 2g.

specific Embodiment approach 3

[0047] A preparation method of nano antibacterial and antivirus plastics, comprising the following sequential steps:

[0048] (1) Combine 6g of rare earth aluminate coupling agent with nano-TiO 2 Put 500g of powder into the drum mixing tank, heat mix at 80°C at 500 rpm for 10 minutes and set aside;

[0049](2) In the drum mixing tank, add 1000g of HIPS resin, 210g of EVA resin with a melt index of 15, and 6g of white mineral oil, mix for 2 minutes at a speed of 500 rpm, and then mix for 1 minute at a speed of 1500 rpm ;

[0050] (3) Add nano-TiO after surface modification in step (1) in the drum mixing tank in step (2) 2 480g, titanium dioxide 100g, zinc stearate 10g, ultramarine blue 2g, network red 0.5g; Then disperse 5 minutes with the rotating speed of 500 rev / min, then 2 minutes with the rotating speed of 1500 rev / min, then discharge the material, use double The screw extruder granulates, the temperature of each section in the screw is 180-200°C, and the screw speed is...

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Abstract

A mother nanoparticle of antibacterial disinfecting plastics is prepared from the TiO2 nanoparticles whose surface is modified by RE aluminate, plastic resin, EVA resin, white mineral oil, titanium white powder, and zinc stearate through proportionally and sequentially mixing, and granulating by extruding out. Its advantage is high antibacterial disinfecting effect.

Description

Technical field [0001] The invention relates to a nano-antibacterial and anti-virus plastic masterbatch, in particular to a nano-TiO 2 Powder nano antibacterial and antivirus plastic masterbatch. The invention also relates to a preparation method of the nano antibacterial and antivirus plastic masterbatch. Background technique [0002] Add nano TiO to plastic 2 It can significantly improve the mechanical properties of plastic materials, and at the same time endow products with certain antibacterial and endotoxin-decomposing functions. Therefore, nano-antibacterial and anti-virus plastics have good application prospects. The existing nano antibacterial and anti-virus plastic materials usually adopt two molding processes, one is to use nano TiO 2 The powder is directly added to the plastic raw material. The process is to simply use liquid paraffin, white mineral oil, etc. for surface bonding treatment, and then directly carry out molding processing; the other is to add nano...

Claims

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Application Information

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IPC IPC(8): C08K9/04C08L101/00
Inventor 张志焜崔作林王兆波叶林忠
Owner HAIER GRP CORP
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