Catalyst for cathode in fuel cell
A fuel cell cathode and catalyst technology, applied in fuel cells, solid electrolyte fuel cells, battery electrodes, etc.
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[0026] In a direct methanol fuel cell (DMFC), the catalyst used for the cathode must have low methanol oxidation reactivity and high oxygen reduction reactivity.
[0027] For the methanol oxidation reaction, the methanol (CH 3 OH) has gone through the reaction steps represented by the following reaction scheme 1:
[0028] Process 1
[0029]
[0030] According to reports, CH 3 The decomposition reaction of O is the rate-determining step in reaction scheme 1 [M. Mavrikakis and M.A. Barteau, J. of Molecular Catalysis A, 131, 135 (1998)]. CH 3 The decomposition temperature of O rises as the binding force between catalyst particles and oxygen increases or as the binding force between catalyst particles and hydrogen decreases [M.A.Barteau, Catal.Lett.8, 175(1991)].
[0031] To reduce the methanol oxidation reactivity of catalyst particles, a high CH 3 O decomposition temperature. In this regard, it is advantageous to increase the binding capacity of the catalyst particl...
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