Clay composition for sintered noble metal objects and method of producing, clay composition for sintered noble metal objects and method of producing sintered noble metal
A precious metal and composition technology, which is applied in the field of producing precious metal sintered bodies, can solve the problems of partial shedding of clay, damage to the appearance of molded products, loosening of decorative parts, etc., and achieves the effects of reducing energy consumption and expanding the range of sintering temperature.
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Embodiment 1
[0033] The mixed silver powder of 92wt% is mixed with the water-soluble binder that is made up of 0.7wt% starch, 0.8wt% cellulose and remainder water, makes clay composition, and the mixed silver powder wherein is made of 50% by weight (46wt% ) silver powder with an average particle diameter of 2.5 μm and 50% by weight (46 wt %) of silver powder with an average particle diameter of 20 μm. The clay composition was molded into a test sample having a size of 50 mm long x 10 mm wide x 1.5 mm thick, and the test sample was sintered under the following conditions. Methylcellulose (manufactured by Shin-etsu Chemical Industry Co., Ltd., sold under the trade name "Methlose SM8000") was used as cellulose, β-potato starch (manufactured by Nichiden Kagaku K.K., sold under the trade name "DELICAM-9") sold) as starch.
[0034] Firing conditions
Degree of shrinkage
(%)
Bending strength
(kgf / mm 2 )
cracked / bent
Evaluation
590℃&5min
...
Embodiment 2
[0046] The mixed gold powder of 94wt% is mixed with the water-soluble binding agent that is made up of 0.5wt% starch, 0.6wt% cellulose and remainder water, makes clay composition, and the mixed gold powder wherein is made of 50% by weight (47wt% ) gold powder with an average particle diameter of 2.5 μm and 50% by weight (47 wt %) of gold powder with an average particle diameter of 20 μm. The clay composition was molded into a test sample having a size of 50 mm long x 10 mm wide x 1.5 mm thick, and the test sample was fired under the following conditions.
[0047] Firing conditions
Degree of shrinkage
(%)
Bending strength
(kgf / mm 2 )
cracked / bent
Evaluation
690℃&5min
5.9
7.98
burst
×
690℃&30min
5.9
8.12
burst
×
700℃&5min
6.7
10.88
to bend
○
700℃&30min
7.8
24.74
to bend
○
750℃&5min
...
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