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Functionalized unimodal radial block copolymer and its preparation method

A block copolymer and radial technology, which is applied in the field of functionalized monomorphic radial block copolymer and its preparation, can solve the problems of low degree of randomness in the gradient segment, long feeding time, and prolonging the feeding time of butadiene, etc. question

Inactive Publication Date: 2006-09-13
PETROCHINA CO LTD
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] Synthesis of a transition segment in a copolymer of monovinylarene and conjugated diene, WO96 / 25442 reports the formation of a transition segment by prolonging the feeding time of butadiene, from continuous feeding of butadiene to discontinuous feeding, and discontinuous feeding of styrene It is obtained by changing the method of continuous feeding and controlling the polymerization temperature. This method takes a long time to feed, and it is necessary to realize alternate control, which is not conducive to industrial production.
Patents EP761704A1, US5399628, etc. refer to the synthesis of the gradient section. In the synthesis of styrene and butadiene, they are mixed in a certain proportion and added at a constant temperature. product performance

Method used

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  • Functionalized unimodal radial block copolymer and its preparation method
  • Functionalized unimodal radial block copolymer and its preparation method
  • Functionalized unimodal radial block copolymer and its preparation method

Examples

Experimental program
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Embodiment 1～10

[0046] In a jacketed 14L stainless steel reactor, the polymerization was carried out in a hydrocarbon solvent under the protection of argon. Continuous stirring of the reaction mixture is required during polymerization and coupling. Adding steps are as follows:

[0047] (1) monovinylarene monomer and initiator;

[0048] (2) A mixture of monovinylarene monomers and conjugated diene monomers (70% to 85% of the total weight of the mixture):

[0049] (3) A mixture of monovinylarene monomers and conjugated diene monomers (the remaining 15% to 30% mixture);

[0050] (4) conjugated diene monomer;

[0051] (5) Coupling agent.

[0052] After the coupling reaction is complete, water and CO 2 The coupled reaction mixture is treated and antioxidants are added prior to obtaining the polymer xylk of the invention. Table 1 shows the types of raw materials and additives used in Examples 1-10, and Table 2 shows the formulations and process conditions for preparing the copolymers of the pre...

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Abstract

The invention provides a functionalized unimodal radial block copolymer and its preparation method whose structure is illustrated by formula AYB#-[3]-(B#-[2]-S#-[3])B#-[1] / S#-[2]-S#-[1]}#-[3]}#-[n], wherein S is styrene single vinyl aromatic hydrocarbons, B is butadiene conjugated diolefin, Y=Si, Sn, n=1, 2, A is hydrocarbon radical with hydroxy, imino, benzene imino, mercapto functional group or polymer chain P.

Description

technical field [0001] The invention relates to a functionalized monomorphic radial block copolymer and a preparation method thereof, in particular to a highly transparent, impact-resistant monomorphic end with a random gradient segment and each polymer molecule contains at least A functional group radial block copolymer and its preparation method. Background technique [0002] In the prior art, there are many related documents reporting on butadiene-styrene block copolymers, such as EP0492490, US 4925899, US 5130377, CN 85100418 and so on. Patent CN 1073950 reports a method for preparing a butadiene-styrene block copolymer. The initiator is added once, and the copolymer is obtained through a coupling reaction, but the molecular chain of the copolymer does not contain a gradient segment, so the coupling efficiency is low , the coupling reaction time is long. The butadiene-styrene block copolymers reported in US 4925899, US 5130377, and CN 85100418 are polymorphic or multim...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08F297/04
Inventor 龚光碧吕爱新杜正银陶惠平贺琼玉陈建刚杨绮波李毅郭义张银娥
Owner PETROCHINA CO LTD
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