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Production of alkyl 6-aminocaproate

A kind of technology of alkyl aminocaproate and alkyl cyanovalerate, applied in the field of producing alkyl 6-aminocaproate and/or caprolactam

Inactive Publication Date: 2006-07-19
INVISTA TECHNOLOG IES S A R L
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Both of the above 2 3PN-based methods will generate a large amount of HMD

Method used

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  • Production of alkyl 6-aminocaproate

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0074] Oxidative esterification of formylvaleronitrile to methyl cyanovalerate

[0075] This example demonstrates that formylvaleronitrile can be converted to methyl cyanovalerate (MCV) in one step with an increase in selectivity towards the linear isomer.

[0076] Contain the sample of the solution of 2.3g formyl valeronitrile (84.4% 5FVN, 3.7% 4FVN and 11.8% 3FVN), 10g methyl alcohol and 0.5g o-dichlorobenzene (GC internal standard) in 10wt% solid catalyst (as shown in table 1 ) in the presence of 50°C and 500 psig air pressure for 1 hour. The product was analyzed by gas chromatography with a Restex(R)-5 amine column (15 m x 0.25 mm). The conversion ratio is shown in Table 1. FVN linearity in the table = 100*5FVN / (3FVN+4FVN+5FVN). MCV linearity = 100*M5CV / (M3CV+M4CV+M5CV).

[0077] PD 4 TeZnPb

Embodiment 2

[0079] Separation of linear and branched methyl cyanovalerate

[0080] This example demonstrates that branched isomers can be removed in a commercially viable distillation process (overhead pressure 10 Torr).

[0081] 300 g of mixed methyl cyanovalerate was used as the feed to a batch distillation column with 20 1 inch trays in a 500 ml volume Oldershaw still. GC analysis found that the feed composition was 14.3% M4CV, 7.7% M3CV and 75.9% M5CV, and the rest was mainly methanol acetal and 5FVN. At 10 torr (1.3×10 -3 MPa) pressure, start distillation under total reflux, and the condenser temperature is 0°C. Low boilers leave the distillation column mainly through the total reflux condenser. Under total reflux, the distillation column reached a steady state with a kettle temperature of 150°C and a tower top temperature of 102°C. The distillate was then collected into several 5 ml fractions with a vapor splitting head at a reflux ratio of 100:1. During the collection of 13 fr...

Embodiment 3

[0083] with Raney  Synthesis of methyl 6-aminocaproate with cobalt catalyst

[0084] This example demonstrates methyl 5-cyanovalerate in Raney  In the presence of cobalt, it can be hydrogenated to 6-aminocaproic acid methyl ester.

[0085] Charge 26.0 g methanol and 0.5 g Raney in a 100 ml stainless steel high pressure stirred reactor (Parr reactor)  Cobalt 2724 (W.R. Grace Company). A cup was then secured to the top of the reactor, pressure tested with 100 psig nitrogen, and purged with hydrogen. It was then pressurized to 250 psig with hydrogen and heated to reaction temperature (75° C.) with constant stirring. 10.23 g of methyl 5-cyanovalerate (M5CV), 0.5 g of 1-methyl-2-pyrrolidone (internal standard) and 5.0 g methanol. The pressure in the reactor was then raised to the desired level (500 psig 3.5 MPa) and maintained at this level throughout the experiment (1.2 hours). During the reaction, 1 ml samples were periodically withdrawn from the reactor through a sampl...

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Abstract

A process for making alkyl 6-aminocaproate by hydroformylating 3-pentenenitrile to produce 3-, 4-, and 5-formylvaleronitrile (FVN mixture), converting the FVN mixture to alkyl 3-, 4-, and 5-cyanovalerate by either oxidative esterification of the FVN mixture or oxidation of the FVN mixture followed by esterification; isolating alkyl 5-cyanovalerate; and hydrogenating the alkyl 5-cyanovalerate to produce alkyl 6-aminocaproate. The resulting alkyl 6-aminocaproate can be cyclized to produce caprolactam.

Description

technical field [0001] The present invention relates to a process for the production of alkyl 6-aminocaproate and / or caprolactam. Background technique [0002] Caprolactam is produced industrially by a process using cyclohexane as a raw material. The caprolactam is then polymerized to produce nylon-6. For reasons of price, it is desirable to produce caprolactam from butadiene, a 4-carbon feedstock, rather than the 6-carbon cyclohexane feedstock used in current industrial processes. [0003] Butadiene is known to react with HCN to form 3-pentenenitrile (3PN). One method of converting 3PN to caprolactam involves converting 3PN to capronitrile (ADN). ADN is then partially hydrogenated to 6-aminocapronitrile, which is then converted to caprolactam by hydrolysis followed by cyclization. See, eg, US Patent 6,069,246. Partial hydrogenation produces large amounts of hexamethylenediamine (HMD). [0004] A second method for converting 3PN to caprolactam involves the reductive am...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C07C227/12C07C229/08C07D223/10C07B61/00C07C227/10
CPCC07C227/12C07C229/08
Inventor E·E·布内尔T·A·科克R·奥泽尔S·K·森古塔
Owner INVISTA TECHNOLOG IES S A R L
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